This review describes the additions of allylmagnesium reagents to carbonyl compounds and
to imines, focusing on the differences in reactivity between allylmagnesium halides and …

Bu3SnH-mediated aryl radical cyclization onto methylenecycloalkanes having a phenylthio,
an ester, or a nitrile group at the terminus of the alkenic bond provides exclusively exo …

The iodine-atom-transfer 8-endo cyclization of α-carbamoyl radicals was investigated
experimentally and theoretically. With the aid of Mg (ClO4) 2 and a bis (oxazoline) ligand, N …

Titanocene (III) chloride (Cp2TiCl) mediated 7-exo and 8-endo radical cyclizations of
epoxides towards the synthesis of 7-and 8-membered cyclic ethers have been described …

Seven‐membered lactones undergo selective SmI2–H2O‐promoted radical cyclization to
form substituted cyclooctanols. The products arise from an exo‐mode of cyclization rather …

The phosphorus based radical precursors N-ethylpiperidine hypophosphite (EPHP) and
diethylphosphine oxide (DEPO) are efficient reagents for carrying out the formation of seven …

While exploring the application of radical cyclizations to the construction of bridged
polycyclic systems, we have discovered a novel tandem process consisting of an endo …

Titanocene (III) chloride (Cp2TiCl) mediated 8-endo radical cyclizations towards the
synthesis of eight-membered cyclic ethers have been described. Titanocene (III) chloride …

The addition of the highly reactive reagent allylmagnesium halide to α-substituted acyclic
chiral ketones proceeded with high stereoselectivity. The stereoselectivity cannot be …

Thiophenol-mediated 7-endo radical cyclization for the synthesis of seven-membered cyclic
ethers is described. This method can be successfully applied to synthesize various …