This Minireview describes recent advances of organophosphorus compounds as opto‐
electronic materials in the field of organic electronics. The progress of (hetero‐) phospholes …

In all likelihood the first synthesis of the phosphaethynolate anion, PCO−, was performed in
1894 when NaPH2 was reacted with CO in an attempt to make Na (CP) accompanied by …

The photochemical activation of the C (sp)–C (sp 2) bond in Pt (0)-η2-aryl-phosphaalkyne
complexes leads selectively to coordination compounds of the type L n Pt (aryl)(C≡ P). The …

New tris-amidinate actinide (Th, U) complexes containing a rare O-bound terminal
phosphaethynolate (OCP−) ligand were synthesized and fully characterized. The cyanate …

Reaction of the trivalent uranium complex [((Ad, MeArO) 3N) U (DME)] with [Na
(OCP)(dioxane) 2.5] and 2.2. 2-crypt yields the μ-oxo-bridged, diuranium complex [Na (2.2. 2 …

The first isolable phosphaalkyne was discovered by Becker, Gresser, and Uhl in 1981. Since
this initial discovery, the chemistry of phosphaalkynes has continuously attracted attention …

Abstract Die erste Synthese des 2‐Phosphaethinolat‐Anions, PCO−, gelang sehr
wahrscheinlich bereits 1894 bei dem Versuch, durch Umsetzung von NaPH2 mit …

Coordination of the diazadiene diolefin ligand (trop2dad) to ruthenium leads to various
complexes of composition [Ru (trop2dad)(L)]. DFT studies indicate that the closed‐shell …

The chemistry of transition metal carbynes, LnM≡ CR, has historically been dominated by
species bearing hydrocarbyl or amino 'R'substituents, with other elements appearing only …

We review the known chemistry of the cyaphide ion,(C≡ P)−. This remarkable diatomic
anion has been the subject of study since the late nineteenth century, however its isolation …