Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications

G Chakraborty, IH Park, R Medishetty… - Chemical Reviews, 2021 - ACS Publications
Among the recent developments in metal-organic frameworks (MOFs), porous layered
coordination polymers (CPs) have garnered attention due to their modular nature and …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Photoreactive crystals exhibiting [2+ 2] photocycloaddition reaction and dynamic effects

BB Rath, JJ Vittal - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Conducting a reaction in the solid state eliminates the usage of solvents. If such
reactions are conducted in a single-crystal to single-crystal (SCSC) fashion, then structural …

Unique proton dynamics in an efficient MOF-based proton conductor

YS Wei, XP Hu, Z Han, XY Dong… - Journal of the …, 2017 - ACS Publications
Recently, research on metal–organic frameworks (MOFs) serving as a new type of proton
conductive material has resulted in many exciting achievements. However, direct …

Topochemical polymerizations for the solid-state synthesis of organic polymers

K Hema, A Ravi, C Raju, JR Pathan, R Rai… - Chemical Society …, 2021 - pubs.rsc.org
Topochemical polymerizations are solid-state reactions driven by the alignment of
monomers in the crystalline state. The molecular confinement in the monomer crystal lattice …

Metal‐organic frameworks in polymer science: polymerization catalysis, polymerization environment, and hybrid materials

BVKJ Schmidt - Macromolecular Rapid Communications, 2020 - Wiley Online Library
The development of metal‐organic frameworks (MOFs) has had a significant impact on
various fields of chemistry and materials science. Naturally, polymer science also exploited …

Supramolecular assembly based on “emerging” intermolecular interactions of particular interest to coordination chemists

ERT Tiekink - Coordination Chemistry Reviews, 2017 - Elsevier
An overview of supramolecular assembly sustained by intermolecular contacts pertinent to
the coordination chemistry community is presented. Herein, the supramolecular …

Cascading effect of large molecular motion in crystals: A topotactic polymorphic transition paves the way to topochemical polymerization

C Raju, GR Ramteke, KVJ Jose… - Journal of the American …, 2023 - ACS Publications
A topochemical polymerization governed by a topotactic polymorphic transition is reported.
A monomer functionalized with azide and an internal alkyne crystallized as an unreactive …

Recent advances in single-crystal-to-single-crystal transformation at the discrete molecular level

A Chaudhary, A Mohammad… - Crystal Growth & Design, 2017 - ACS Publications
The present review focuses on the solid state structural transformations in discrete
molecules. Since the molecules in the crystal lattice are closely packed, any transformation …

Stereoselective Solid‐State Synthesis of Substituted Cyclobutanes Assisted by Pseudorotaxane‐like MOFs

FL Hu, Y Mi, C Zhu, BF Abrahams… - Angewandte …, 2018 - Wiley Online Library
Regioselective photodimerization of trans‐4‐styrylpyridine (4‐spy) derivatives is performed
using pseudorotaxane‐like Zn‐based metal organic frameworks MOFs as templates. The …