Model Compounds for Intermediates and Transition States in Sonogashira and Negishi Coupling: d8d10 Bonds in Large Heterobimetallic Complexes Are Weaker …

RJ Oeschger, R Bissig, P Chen - Journal of the American …, 2022 - ACS Publications
We report an experimental study, with accompanying DFT calculations, on a series of
heterobimetallic complexes with Pd (II) and Cu (I), Ag (I), or Au (I). The isolable pincer …

Switching the spin-crossover phenomenon by ligand design on imidazole–diazineiron (II) complexes

N Bibi, EGR de Arruda, A Domingo, AA Oliveira… - Inorganic …, 2018 - ACS Publications
The iron (II) complexes of two structural isomers of 2-(1 H-imidazol-2-yl) diazine reveal how
ligand design can be a successful strategy to control the electronic and magnetic properties …

[HTML][HTML] An extended π-system and enhanced electronic delocalization on symmetric [Ru 3 O (CH 3 COO) 6 (L) 3] n complexes combined with azanaphthalene …

B Possato, VM Deflon, Z Naal, ALB Formiga… - Dalton …, 2017 - pubs.rsc.org
We report on the investigation of a new series of symmetric trinuclear ruthenium complexes
combined with azanaphthalene ligands:[Ru3O (CH3COO) 6 (L) 3] PF6 where L=(1) …

Assessment of the electronic structure of a triruthenium acetate-pyridylnaphthalimide cluster

DBG Mateus, S da Silva Souza… - … of Photochemistry and …, 2020 - Elsevier
A synthetic route for attaining the combination of an electroactive unit with the chromophore
N-(4-pyridyl)-1, 8-naphthalimide (NI-py) was developed, yielding the trinuclear ruthenium …

Synthesis, characterization and introduction of a new ion-coordinating ruthenium sensitizer dye in quasi-solid state TiO2 solar cells

RC White, JE Benedetti, AD Gonçalves… - … of Photochemistry and …, 2011 - Elsevier
A new ion-coordinating heteroleptic ruthenium (II) dye was synthesized by attaching two
crown ether moieties in the 4, 4′ positions of one of the bipyridine ligands. This new dye …

Gas‐phase behaviour of Ru (II) cyclopentadienyl‐derived complexes with N‐coordinated ligands by electrospray ionization mass spectrometry: fragmentation …

PJA Madeira, TS Morais, TJL Silva… - Rapid …, 2012 - Wiley Online Library
RATIONALE The gas‐phase behaviour of six Ru (II) cyclopentadienyl‐derived complexes
with N‐coordinated ligands, compounds with antitumor activities against several cancer …

Corrole isomers: intrinsic gas-phase shapes via traveling wave ion mobility mass spectrometry and dissociation chemistries via tandem mass spectrometry

M Fasciotti, AF Gomes, FC Gozzo, BA Iglesias… - Organic & …, 2012 - pubs.rsc.org
Corrole and four of its isomers with subtle structural changes promoted by exchange of
nitrogen and carbon atoms in the corrole ring have been studied by traveling wave ion …

Direct assembly of a metallodendrimer encompassing seven triruthenium clusters units

SH Toma, JJ Santos, S Nikolaou, K Araki… - Inorganica Chimica …, 2012 - Elsevier
A general strategy for the assembly of dendrimeric metallo-cluster species based on tritopic
trinuclear ruthenium acetate complexes is demonstrated. First, a central core consisting of a …

Electroactive chain-like compounds constructed from trimetallic clusters and 4, 4′-bipyridine spacers: one-pot synthesis, characterization and surface binding

M Abe, A Inatomi, Y Hisaeda - Dalton Transactions, 2011 - pubs.rsc.org
This paper reports the synthesis and characterization of a novel series of chain-like
compounds where oxo-centered triruthenium cluster moieties are bridged by 4, 4 …

A Convergent Approach for the Generation of Dendrimers Containing the [Ru3O(CH3COO)6] Electroactive Core

S Nikolaou, HE Toma - 2008 - Wiley Online Library
We report on a convergent approach for the generation of dendrimers containing the [Ru3O
(ac) 6] electroactive core, of great interest as multielectron transfer catalysts. The proposed …