Molecular photoswitches in aqueous environments
Molecular photoswitches enable dynamic control of processes with high spatiotemporal
precision, using light as external stimulus, and hence are ideal tools for different research …
precision, using light as external stimulus, and hence are ideal tools for different research …
Taking phototherapeutics from concept to clinical launch
BM Vickerman, EM Zywot, TK Tarrant… - Nature Reviews …, 2021 - nature.com
More than four decades have passed since the first example of a light-activated (caged)
compound was described. In the intervening years, a large number of light-responsive …
compound was described. In the intervening years, a large number of light-responsive …
Photochromism into nanosystems: towards lighting up the future nanoworld
L Wang, Q Li - Chemical Society Reviews, 2018 - pubs.rsc.org
The ability to manipulate the structure and function of promising nanosystems via energy
input and external stimuli is emerging as an attractive paradigm for developing …
input and external stimuli is emerging as an attractive paradigm for developing …
Stepping out of the blue: from visible to near‐IR triggered photoswitches
Z Zhang, W Wang, M O'Hagan, J Dai… - Angewandte Chemie …, 2022 - Wiley Online Library
Light offers unique opportunities for controlling the activity of materials and biosystems with
high spatiotemporal resolution. Molecular photoswitches are chromophores that undergo …
high spatiotemporal resolution. Molecular photoswitches are chromophores that undergo …
Visible light-responsive materials: the (photo) chemistry and applications of donor–acceptor Stenhouse adducts in polymer science
M Clerc, S Sandlass, O Rifaie-Graham… - Chemical Society …, 2023 - pubs.rsc.org
Donor–acceptor Stenhouse adduct (DASA) photoswitches have gained a lot of attention
since their discovery in 2014. Their negative photochromism, visible light absorbance …
since their discovery in 2014. Their negative photochromism, visible light absorbance …
The (photo) chemistry of Stenhouse photoswitches: guiding principles and system design
Molecular photoswitches comprise chromophores that can be interconverted reversibly with
light between two states with different photochemical and physicochemical properties. This …
light between two states with different photochemical and physicochemical properties. This …
General Principles for the Design of Visible‐Light‐Responsive Photoswitches: Tetra‐ortho‐Chloro‐Azobenzenes
Molecular photoswitches enable reversible external control of biological systems,
nanomachines, and smart materials. Their development is driven by the need for low energy …
nanomachines, and smart materials. Their development is driven by the need for low energy …
Controlling dark equilibria and enhancing donor–acceptor Stenhouse adduct photoswitching properties through carbon acid design
A novel library of tunable negative photochromic compounds, donor–acceptor Stenhouse
adducts (DASAs), is reported. Tailoring the electron deficient “acceptor” moiety yielded …
adducts (DASAs), is reported. Tailoring the electron deficient “acceptor” moiety yielded …
New molecular switch architectures
JD Harris, MJ Moran… - Proceedings of the …, 2018 - National Acad Sciences
In this paper we elaborate on recently developed molecular switch architectures and how
these new systems can help with the realization of new functions and advancement of …
these new systems can help with the realization of new functions and advancement of …
A multi-stage single photochrome system for controlled photoswitching responses
The ability of molecular photoswitches to convert on/off responses into large macroscale
property change is fundamental to light-responsive materials. However, moving beyond …
property change is fundamental to light-responsive materials. However, moving beyond …