Ligands for f-element extraction used in the nuclear fuel cycle

A Leoncini, J Huskens, W Verboom - Chemical Society Reviews, 2017 - pubs.rsc.org
Liquid–liquid extraction is the major technique being applied for the partitioning of f-
elements from nuclear waste. In this review, the recent developments in ligand design …

An overview of molecular extractants in room temperature ionic liquids and task specific ionic liquids for the partitioning of actinides/lanthanides

M Iqbal, K Waheed, SB Rahat, T Mehmood… - … of Radioanalytical and …, 2020 - Springer
Solvent extraction process is applied for the extraction of actinides/lanthanides from waste
water produced in nuclear industry. Various extractants have been developed for this …

[图书][B] Ion Exchange and Solvent Extraction: A Series of Advances, Volume 19

BA Moyer - 2009 - taylorfrancis.com
The growth in the world's nuclear industry, motivated by peaking world oil supplies,
concerns about the greenhouse effect, and domestic needs for energy independence, has …

Separation of plutonium from other actinides and fission products in ionic liquid medium

A Rout - Separation & Purification Reviews, 2023 - Taylor & Francis
Recovery of plutonium from spent nuclear fuels is very much indispensable in fast neutron
reactor fuel reactor wherein, plutonium–239 (239Pu) is used as the driving fuel. Separation …

Hexavalent americium recovery using copper (III) periodate

K McCann, DM Brigham, S Morrison… - Inorganic …, 2016 - ACS Publications
Separation of americium from the lanthanides is considered one of the most difficult
separation steps in closing the nuclear fuel cycle. One approach to this separation could …

Unusual extraction of plutonium (IV) from uranium (VI) and americium (III) using phosphonate based task specific ionic liquid

A Rout, KA Venkatesan, TG Srinivasan… - Radiochimica …, 2010 - degruyter.com
A task specific ionic liquid (TSIL), diethyl-2-(3-methylimidazolium) ethylphosphonate bis (
trifluoromethanesulfonyl) imide, ImPNTf2, was synthesized and characterized by 1H, 13C …

Diamylamylphosphonate solvent extraction of Am (VI) from nuclear fuel raffinate simulant solution

BJ Mincher, LR Martin, NC Schmitt - Solvent extraction and ion …, 2012 - Taylor & Francis
The separation of hexavalent americium from the lanthanides in simulated PUREX raffinate
solution using 1 M diamylamylphosphonate in dodecane extraction was investigated …

Studies on the extraction of actinides by substituted butyl phosphonates

CVS Brahmmananda Rao, TG Srinivasan… - … Extraction and Ion …, 2012 - Taylor & Francis
The extraction of actinides by homologs of dibutylalkyl phosphonates has been studied in
detail. This study was taken up in order to understand the influence of the phosphorus …

Solubility of di-cyclohexylhydrogen phosphonate in supercritical carbon dioxide medium: Application towards the recovery of uranium from aqueous solution

P Rajani, KC Pitchaiah, B Sreenivasulu… - Journal of Molecular …, 2023 - Elsevier
Hydrogen phosphonates are di-esters of phosphonic acids and are widely employed as
ligands for recovery of actinide species from different matrices. An alicyclic hydrogen …

Solubilities of dialkylhydrogen phosphonates in supercritical carbon dioxide and their correlation using semi-empirical equations

J Deepitha, KC Pitchaiah… - Separation Science …, 2019 - Taylor & Francis
The solubilities of dibutylhydrogen phosphonate (DBHP) and dihexylhydrogen phosphonate
(DHHP) in supercritical carbon dioxide were determined at 313–333 K and 10–20 MPa. The …