Heterogeneous photochemistry in the atmosphere

C George, M Ammann, B D'Anna… - Chemical …, 2015 - ACS Publications
1. BACKGROUND 1.1. Why Condensed Matter Matters: Types and Significance of
Condensed Matter and Surfaces Encountered in the Atmospheric Environment The …

Tropospheric halogen chemistry: Sources, cycling, and impacts

WR Simpson, SS Brown, A Saiz-Lopez… - Chemical …, 2015 - ACS Publications
In the past 40 years, atmospheric chemists have come to realize that halogens exert a
powerful influence on the chemical composition of the troposphere and through that …

Halogens and their role in polar boundary-layer ozone depletion

WR Simpson, R Von Glasow, K Riedel… - Atmospheric …, 2007 - acp.copernicus.org
During springtime in the polar regions, unique photochemistry converts inert halide salt ions
(eg Br−) into reactive halogen species (eg Br atoms and BrO) that deplete ozone in the …

An overview of snow photochemistry: evidence, mechanisms and impacts

AM Grannas, AE Jones, J Dibb… - Atmospheric …, 2007 - acp.copernicus.org
It has been shown that sunlit snow and ice plays an important role in processing
atmospheric species. Photochemical production of a variety of chemicals has recently been …

Atmospheric budget of acetone

DJ Jacob, BD Field, EM Jin, I Bey, Q Li… - Journal of …, 2002 - Wiley Online Library
The atmospheric budget and distribution of acetone are investigated by using a priori
estimates of sources and sinks to constrain a global three‐dimensional atmospheric model …

The role of the global cryosphere in the fate of organic contaminants

AM Grannas, C Bogdal, KJ Hageman… - Atmospheric …, 2013 - acp.copernicus.org
The cryosphere is an important component of global organic contaminant cycles. Snow is an
efficient scavenger of atmospheric organic pollutants while a seasonal snowpack, sea ice …

Formation of hydroxyl radical from the photolysis of frozen hydrogen peroxide

L Chu, C Anastasio - The Journal of Physical Chemistry A, 2005 - ACS Publications
Hydrogen peroxide (HOOH) in ice and snow is an important chemical tracer for the oxidative
capacities of past atmospheres. However, photolysis in ice and snow will destroy HOOH and …

High levels of molecular chlorine in the Arctic atmosphere

J Liao, LG Huey, Z Liu, DJ Tanner, CA Cantrell… - Nature …, 2014 - nature.com
Chlorine radicals can function as a strong atmospheric oxidant,,, particularly in polar
regions, where levels of hydroxyl radicals are low. In the atmosphere, chlorine radicals …

Atmospheric VOC measurements at a High Arctic site: characteristics and source apportionment

JB Pernov, R Bossi, T Lebourgeois… - Atmospheric …, 2021 - acp.copernicus.org
There are few long-term datasets of volatile organic compounds (VOCs) in the High Arctic.
Furthermore, knowledge about their source regions remains lacking. To address this matter …

Processes and properties of snow–air transfer in the high Arctic with application to interstitial ozone at Alert, Canada

MR Albert, AM Grannas, J Bottenheim… - Atmospheric …, 2002 - Elsevier
Recent measurements of reactive chemical species in snow and firn at polar sites have
served to underscore the importance of air–snow transfer processes in understanding …