This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

This Perspective article summarizes recent progress from our laboratory in the isolation of
reactive main group species using a general donor–acceptor protocol. A highlight of this …

Mild thermolysis of Lewis base stabilized phosphinoborane monomers R1R2P BH2⋅
NMe3 (R1, R2= H, Ph, or tBu/H) at room temperature to 100° C provides a convenient new …

The reaction of the Lewis base‐stabilized phosphinoborane monomer tBuHPBH2NMe3 (2
a) with catalytic amounts of bis (η5: η1‐adamantylidenepentafulvene) titanium (1) provides a …

A comprehensive reactivity study of gallapnictenes LGaEGa (Cl) L (E= As, Sb; L= HC [C
(Me) N (Ar)] 2, Ar= Dip= 2, 6‐i‐Pr2C6H3) proved the nucleophilic character of the pnictogen …

Structures and stability of mixed group 13–14–15 element hydrides PBEH6 (E= C, Si, Ge),
their oligomers, and complexes with Lewis acids and Lewis base are computationally …

The synthesis and characterization of the unprecedented compounds IDipp⋅ E′ H2AsH2
(E′= Al, Ga; IDipp= 1, 3‐bis (2, 6‐diisopropylphenyl) imidazolin‐2‐ylidene) are reported …

The synthesis and characterization of the first parent phosphanylalane and
phosphanylgallane stabilized only by a Lewis base (LB) are reported. The corresponding …

The thermal dehydrogenative coupling of aryl phosphine–borane adducts with iridium
complexes bearing a bis (phosphinite) pincer ligand is reported. This catalysis produces …

In the present review recent advances in the chemistry of group 13 Lewis acids, such as
intermolecular complexes with donor–acceptor metal–metal bonds, bifunctional Lewis acids …