Throughout inorganic and organometallic chemistry few ligands have been as widely
employed as tertiary mono-and diphosphines]~ It is still perhaps true to say that the most …

The synthesis and coordination chemistry of bis-and tris (phosphines) with P Si P, P O
Si O P and P C Si C P linkages is reviewed. The catalytic reactions involving …

Reactions of N-aryl and N-alicyclic derivatives of aminophosphines with paraformaldehyde
lead to methylene insertion into P− N bond followed by oxidation of phosphorus from the P …

Three series of palladium (II) complexes supported by a phosphine‐iminophosphorane
ligand built upon an ortho‐phenylene core were investigated to study the influence of the …

Cyclodiphosphazanes having hemilabile ponytails such as cis-[t BuNP (OC6H4OMe-o)] 2
(2), cis-[t BuNP (OCH2CH2OMe)] 2 (3), cis-[t BuNP (OCH2CH2SMe)] 2 (4), and cis-[t BuNP …

The reaction of p-phenylenediamine with excess PCl3 in the presence of pyridine affords p-
C6H4 [N (PCl2) 2] 2 (1) in good yield. Fluorination of 1 with SbF3 produces p-C6H4 [N (PF2) …

The half-sandwich complexes [(η5-C5H5) RuCl (DPEphos)](1) and [{(η6-p-cymene) RuCl2}
2 (μ-DPEphos)](2) were synthesized by the reaction of bis (2-(diphenylphosphino) phenyl) …

Three‐coordinated chlorogermylenes of the type [Ph2P (RN) 2] GeCl (3: R= tBu; 4: R= Dip=
2, 6‐iPr2C6H3), which bear an N, N‐substituted iminophosphonamide ligand, were …

Iminophosphoranes of general formula Ph 3 P= NC 6 H 4 SR [R= 4-C 6 H 4 NO 2 (3) and
CH 2 C 6 H 5 (4)], combining the iminophosphorane group with a thioether moiety were …

The reaction of aminophosphines and aminobis (phosphines) with aldehydes leads to either
insertion of carbon fragments into the P (III)–N bonds or formation of α-hydroxyphosphine …