The area of catalysis of radical reactions has recently flourished. Various reaction conditions
have been discovered and explained in terms of catalytic cycles. These cycles rarely stand …

Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Conspectus Arene synthesis has been revolutionized by the invention of catalytic cross-
coupling reactions, wherein aryl halides can be coupled with organometallic and organic …

A new transformation is presented that enables chemists to couple simple alkyl carboxylic
acids with aryl zinc reagents under Ni-catalysis. The success of this reaction hinges on the …

Transition metal-catalyzed cross-coupling reactions of organic electrophiles and
organometallic reagents have emerged as a tremendously powerful synthetic tool, and the …

Research in the mid 1960s to early 1970s sparked an evolution in the approach of synthetic
chemists toward the assembly of molecules. Inspired by known Wacker-type processes in …

REVIEW intricate molecular topologies and architectures. To turn the molecular dreams into
a reality, synthetic chemists must ultimately roll up their sleeves and become molecular …

Development of visible light-mediated atom transfer radical addition of haloalkanes onto
unsaturated hydrocarbons has seen rapid growth in recent years. However, due to its radical …

Catalytic cross-coupling reactions have had a profound impact on the synthesis of
pharmaceuticals, biologically active natural products, and materials. 1 Such reactions …

Transition metal-catalysed cross-coupling reactions are widely used for construction of
carbon–carbon and carbon–heteroatom bonds. However, compared to aryl or alkenyl …