σ‐Hole Interactions in Catalysis

M Breugst, JJ Koenig - European Journal of Organic Chemistry, 2020 - Wiley Online Library
Noncovalent interactions like halogen, chalcogen, and pnictogen bonding are known for a
very long time. During the last decade, these interactions have found different applications in …

Catalysis of organic reactions through halogen bonding

RL Sutar, SM Huber - ACS Catalysis, 2019 - ACS Publications
Halogen bonding, the noncovalent interaction based on electrophilic halogen substituents,
features very interesting properties, as illustrated by numerous applications continuously …

Halogen bonding in solution: NMR spectroscopic approaches

D von der Heiden, A Vanderkooy, M Erdelyi - Coordination Chemistry …, 2020 - Elsevier
A halogen bond is a non-covalent interaction between an electron deficient halogen atom
and a nucleophilic region of a molecule [1]. The halogen bearing molecule is referred to as …

Chalcogen bonding catalysis of a nitro‐Michael reaction

P Wonner, A Dreger, L Vogel… - Angewandte Chemie …, 2019 - Wiley Online Library
Chalcogen bonding is the non‐covalent interaction between Lewis acidic chalcogen
substituents and Lewis bases. Herein, we present the first application of dicationic tellurium …

A bidentate iodine (III)‐based halogen‐bond donor as a powerful organocatalyst

F Heinen, DL Reinhard, E Engelage… - Angewandte Chemie …, 2021 - Wiley Online Library
In contrast to iodine (I)‐based halogen bond donors, iodine (III)‐derived ones have only
been used as Lewis acidic organocatalysts in a handful of examples, and in all cases they …

Carbonyl activation by selenium‐and tellurium‐based chalcogen bonding in a Michael addition reaction

P Wonner, T Steinke, L Vogel… - Chemistry–A European …, 2020 - Wiley Online Library
In the last years the use of chalcogen bonding—the noncovalent interaction involving
electrophilic chalcogen centers—in noncovalent organocatalysis has received increased …

Bidentate chiral bis (imidazolium)‐based halogen‐bond donors: synthesis and applications in enantioselective recognition and catalysis

RL Sutar, E Engelage, R Stoll… - Angewandte Chemie …, 2020 - Wiley Online Library
Even though halogen bonding—the noncovalent interaction between electrophilic halogen
substituents and Lewis bases—has now been established in molecular recognition and …

Organocatalytic Friedel–Crafts arylation of aldehydes with indoles utilizing N-heterocyclic iod (az) olium salts as halogen-bonding catalysts

EM Galathri, TJ Kuczmera, BJ Nachtsheim… - Green …, 2024 - pubs.rsc.org
The Friedel–Crafts arylation is among the most known organic reactions, usually being
promoted by a Lewis acid, that have been employed for the synthesis of bis-indolyl …

Halogen bond-catalyzed Friedel–Crafts reactions of aldehydes and ketones using a bidentate halogen bond donor catalyst: synthesis of symmetrical bis (indolyl) …

X Liu, S Ma, PH Toy - Organic letters, 2019 - ACS Publications
The use of a halogen bond donor to catalyze Friedel–Crafts reactions of indoles with a
range of aldehydes and ketones to directly produce bis (indolyl) methanes, including the …

Balancing Activity and Stability in Halogen-Bonding Catalysis: Iodopyridinium-Catalyzed One-Pot Synthesis of 2, 3-Dihydropyridinones

Y Li, Y Ge, R Sun, X Yang, S Huang… - The Journal of …, 2023 - ACS Publications
A one-pot cascade reaction for 2, 3-dihydropyridinone synthesis was accomplished with 3-
fluoro-2-iodo-1-methylpyridinium triflate as the halogen bond catalyst. The desired [4+ 2] …