NHC–Ru complexes—Friendly catalytic tools for manifold chemical transformations

V Dragutan, I Dragutan, L Delaude… - Coordination chemistry …, 2007 - Elsevier
N-Heterocyclic carbenes are now commonly encountered in organometallic and inorganic
coordination chemistry. The increasing attention they enjoy is due to their ability to act as …

Aminophosphines: their chemistry and role as ligands and synthons

J Gopalakrishnan - Applied Organometallic Chemistry, 2009 - Wiley Online Library
In recent years, research in organophosphorus chemistry has mainly focused in designing
newer and better phosphorus ligands for synthesizing novel metal complexes with improved …

pH-dependent selective transfer hydrogenation of α, β-unsaturated carbonyls in aqueous media utilizing half-sandwich ruthenium (II) complexes

CA Mebi, RP Nair, BJ Frost - Organometallics, 2007 - ACS Publications
Half-sandwich ruthenium (II) PTA complexes bearing the 1, 2-dihydropentalenyl (C8H9-, Dp)
and indenyl (C9H7-, Ind) ancillary ligands have been synthesized and characterized using …

Stable group 8 metal porphyrin mono-and bis (dialkylcarbene) complexes: synthesis, characterization, and catalytic activity

HX Wang, Q Wan, KH Low, CY Zhou, JS Huang… - Chemical …, 2020 - pubs.rsc.org
Alkyl-substituted carbene (CHR or CR2, R= alkyl) complexes have been extensively studied
for alkylcarbene (CHR) ligands coordinated with high-valent early transition metal ions (aka …

Iron-catalyzed stereospecific olefin synthesis by direct coupling of alcohols and alkenes with alcohols

ZQ Liu, Y Zhang, L Zhao, Z Li, J Wang, H Li… - Organic Letters, 2011 - ACS Publications
An efficient Fe (III)-catalyzed direct coupling of alkenes with alcohols and cross-coupling of
alcohols with alcohols to give the corresponding substituted (E)-alkenes stereospecifically is …

Synthesis and characterization of a stable high-valent cobalt carbene complex

JA Bellow, SA Stoian, J van Tol… - Journal of the …, 2016 - ACS Publications
The formally CoIV carbene Co (OR) 2 ( CPh2) is formed upon the reaction of
diphenyldiazomethane with the cobalt bis (alkoxide) precursor Co (OR) 2 (THF) 2. Structural …

C−C Coupling and C−H Bond Activation Reactions of Cyclopentadienyl−Osmium Compounds:  The Rich and Varied Chemistry of Os(η5-C5H5)Cl(PiPr3)2 and …

MA Esteruelas, AM López - Organometallics, 2005 - ACS Publications
The six-coordinate osmium (IV) complex OsH2Cl2 (PiPr3) 2 reacts with cyclopentadienyl
derivatives of s-or p-block elements to afford cyclopentadienyl− osmium complexes …

Synthesis, characterization, catalytic oxidation and biological activity of ruthenium (III) Schiff base complexes derived from 3-acetyl-6-methyl-2H-pyran-2, 4 (3H)-dione

S Kannan, R Ramesh - Polyhedron, 2006 - Elsevier
A series of air stable low spin Ru (III) complexes of the type [RuX2 (EPh3) 2 (L)](where X= Cl
or Br; E= P or As; L= monobasic bidentate Schiff base ligand) have been synthesized from …

Sterically Demanding Phosphines with 2,6-Dibenzhydryl-4-methylphenyl Core: Synthesis of RuII, PdII, and PtII Complexes, and Structural and Catalytic Studies

MK Pandey, JT Mague, MS Balakrishna - Inorganic Chemistry, 2018 - ACS Publications
The synthesis of sterically demanding aminophosphine and phosphinite ligands Ar*
NHPPh2 (1) and Ar* OPPh2 (2), based on 2, 6-dibenzhydryl-4-methylphenyl core having …

Metal‐Free and Recyclable Route to Synthesize Polysubstituted Olefins via CC Bond Construction from Direct Dehydrative Coupling of Alcohols or Alkenes with …

F Han, L Yang, Z Li, Y Zhao… - Advanced Synthesis & …, 2014 - Wiley Online Library
A direct synthesis of polysubstituted olefins via construction of C C bonds, which involves
the direct dehydrative coupling of alcohols or alkenes with alcohols, was realized using a …