This article reviews the history and the current state of knowledge concerning the ability of
the heavy chalcogen atoms S and Se, and to some extent Te, to participate in a H-bond as …

The halogen‐bonding interaction is one of the rising stars in supramolecular chemistry.
Although other weak interactions and their influence on the structure and chemistry of …

Halide perovskites provide a versatile platform for exploring the effect of non-covalent
interactions, including halogen bonding, on material properties such as band gap …

This review is focused on a special class of metal complexes where polyhalide units are
either coordinated to metal (“true polyhalide complexes”) or form specific associates with …

Reported is the synthesis and characterization of eight new halotellurate (IV) compounds
consisting of isolated [TeX6] 2−(X= Cl, Br) octahedra charge balanced by halopyridinium …

Reaction of the Al/P-based frustrated Lewis pair (FLP) Mes2P-C ( CH-C6H5)-Al (CMe3) 2
1 with heavier chalcogens (E= S, Se and Te) yielded by oxidation of the P atoms the …

Two trialkylbismuthines BiR3 (R= Me (1), i-Pr (2)) were structurally characterized by single-
crystal X-ray diffraction. Single crystals were grown using an IR-laser-assisted technique. 1 …

Since its discovery 200 years ago, in 1817, by Jöns Jacob Berzelius (1779–1848), the
element selenium has had a rather chequered relationship with biology and medicine, an …

The stoichiometrically controlled halogenation of the intramolecularly coordinated
diaryltelluride (8-Me2NC10H6) 2Te using SO2Cl2, Br2 and I2 was studied. At an equimolar …

Selenium moieties are conveniently introduced into an organic molecule using electrophilic
selenenylating reagents and the process is generally highly chemo‐, regio and …