Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Ligand design in ligand‐protected gold nanoclusters

B Zhang, J Chen, Y Cao, OJH Chai, J Xie - Small, 2021 - Wiley Online Library
The design of surface ligands is crucial for ligand‐protected gold nanoclusters (Au NCs).
Besides providing good protection for Au NCs, the surface ligands also play the following …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Unraveling the impact of gold (I)–thiolate motifs on the aggregation‐induced emission of gold nanoclusters

Z Wu, Q Yao, OJH Chai, N Ding, W Xu… - Angewandte …, 2020 - Wiley Online Library
Aggregation‐induced emission (AIE) provides an efficient strategy to synthesize highly
luminescent metal nanoclusters (NCs), however, rational control of emission energy and …

Visible to NIR‐II Photoluminescence of Atomically Precise Gold Nanoclusters

Z Liu, L Luo, R Jin - Advanced Materials, 2024 - Wiley Online Library
Atomically precise gold nanoclusters (NCs) have emerged as a new class of precision
materials and attracted wide interest in recent years. One of the unique properties of such …

Atomically precise metal nanoclusters: stable sizes and optical properties

R Jin - Nanoscale, 2015 - pubs.rsc.org
Controlling nanoparticles with atomic precision has long been a major dream of
nanochemists. Breakthroughs have been made in the case of gold nanoparticles, at least for …

Engineering functional metal materials at the atomic level

Q Yao, X Yuan, T Chen, DT Leong, J Xie - Advanced Materials, 2018 - Wiley Online Library
With continuous research efforts devoted into synthesis and characterization chemistry of
functional nanomaterials in the past decades, the development of metal materials is …

Precise synthesis, functionalization and application of thiolate-protected gold clusters

W Kurashige, Y Niihori, S Sharma, Y Negishi - Coordination Chemistry …, 2016 - Elsevier
Thiolate-protected gold clusters (Au n (SR) m) have received significant attention as new
functional nanomaterials because they exhibit size-specific physical and chemical …

Luminescent noble metal nanoclusters as an emerging optical probe for sensor development

X Yuan, Z Luo, Y Yu, Q Yao, J Xie - Chemistry–An Asian …, 2013 - Wiley Online Library
In the past few years, highly luminescent noble metal nanoclusters (eg, Au and Ag NCs or
Au/Ag NCs in short) have emerged as a class of promising optical probes for the …

Ultrasmall noble metal nanoparticles: Breakthroughs and biomedical implications

X Jiang, B Du, Y Huang, J Zheng - Nano today, 2018 - Elsevier
As a bridge between individual atoms and large plasmonic nanoparticles, ultrasmall (core
size< 3 nm) noble metal nanoparticles (UNMNPs) have been serving as model for us to …