This review summarizes the recent developments regarding the use of uranium as nuclear
fuel, including recycling and health aspects, elucidated from a chemical point of view, ie …

Understanding and exploiting the redox properties of uranium is of great importance
because uranium has a wide range of possible oxidation states and holds great potential for …

This review is dedicated to the chemistry of stable and isolable species that bear two lone
pairs at the same C center, ie, geminal dianions, stabilized by main group elements. Three …

The power of quantum chemistry to predict the ground and excited state properties of
complex chemical systems has driven the development of computational quantum chemistry …

Diphosphonioalkylidene dianions have emerged as highly effective ligands for lanthanide
and actinide ions, and the resulting formal metal–carbon double bonds have challenged …

The significant interest in actinide bonding has recently focused on novel compounds with
exotic oxidation states. However, the difficulty in obtaining relevant high-quality experimental …

The high stability of the+ IVoxidation state limits thorium redox reactivity. Here we report the
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …

This Perspective provides a detailed overview of the chemistry of low-valent (di-and
trivalent) uranium. The reactivity of uranium (II) and uranium (III) complexes is discussed …

Organoplutonium chemistry was established in 1965, yet structurally authenticated
plutonium–carbon bonds remain rare being limited to π-bonded carbocycle and σ-bonded …

The catalytic activity of the metallacycle thorium amide [(Me3Si) 2N] 2Th [κ2–(N, C)–CH2Si
(CH3) 2N (SiMe3)](Th1) is presented for the selective dihydroboration of nitriles (—C≡ N) …