The discovery that some bis-(phthalocyaninato) lanthanide complexes are molecular
magnets triggered interest in lanthanide ion complexes. Theoretical and experimental …

Conspectus A characteristic phenomenon of lanthanide–fullerene interactions is the transfer
of metal valence electrons to the carbon cage. With early lanthanides such as La, a …

Engineering intramolecular exchange interactions between magnetic metal atoms is a
ubiquitous strategy for designing molecular magnets. For lanthanides, the localized nature …

Single-molecule magnets (SMMs) showing magnetic blocking near or above liquid nitrogen
temperature have recently been achieved by inducing exceptionally strong and axial crystal …

Single-molecule magnets (SMMs) are molecules that can retain magnetic polarization in the
absence of an external magnetic field and embody the ultimate size limit for spin-based …

Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

Fullerenes and endohedral metallofullerenes (EMFs) are exceptional compounds of
outstanding interest in many fields for their physicochemical properties, including material …

Azafullerenes derived from nitrogen substitution of carbon cage atoms render direct
modifications of the cage skeleton, electronic, and physicochemical properties of fullerene …

This article outlines the magnetic properties of single molecule magnets based on Dy-
encapsulating endohedral metallofullerenes. The factors that govern these properties, such …

Abstract The azafullerene Tb2@ C79N is found to be a single‐molecule magnet with a high
100‐s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic …