Graphic, Quantitation, Visualization, Standardization, Digitization, and Intelligence of Electrolyte and Electrolyte‐Electrode Interface

T Cai, Y Wang, F Zhao, Z Ma, P Kumar… - Advanced Energy …, 2024 - Wiley Online Library
Electrolytes have recently regained significant attention in rechargeable batteries due to the
discovery that the electrolyte microstructures play a determinant role in battery performance …

Hybrid Aqueous/Non‐aqueous Electrolytes for Lithium‐Ion and Zinc‐Ion Batteries: A Mini‐Review

C Zhang, Z Cai, R Huang, H Pan - Batteries & Supercaps, 2023 - Wiley Online Library
In recent years, the development of aqueous lithium‐ion batteries and aqueous zinc‐ion
batteries has received extensive attention thanks to the advantages of high safety …

Solvent-assisted hopping mechanism enables ultrafast charging of lithium-ion batteries

X Huang, R Li, C Sun, H Zhang, S Zhang, L Lv… - ACS Energy …, 2022 - ACS Publications
Fast charging is regarded as one of the most coveted technologies for commercial Li-ion
batteries (LIBs), but the lack of suitable electrolytes with sufficient ionic conductivity and …

The hydrogen-bonding dynamics of water to a nitrile-functionalized electrode is modulated by voltage according to ultrafast 2D IR spectroscopy

MJ Ryan, N Yang, K Kwac… - Proceedings of the …, 2023 - National Acad Sciences
We report the hydrogen-bonding dynamics of water to a nitrile-functionalized and plasmonic
electrode surface as a function of applied voltage. The surface-enhanced two-dimensional …

Molecular Level Origin of Ion Dynamics in Highly Concentrated Electrolytes

K Shigenobu, S Tsuzuki, F Philippi… - The Journal of …, 2023 - ACS Publications
Single-ion conducting liquid electrolytes are key to achieving rapid charge/discharge in Li
secondary batteries. The Li+ transference (or transport) numbers are the defining properties …

Coupled ion transport in concentrated PEO–LiTFSI polymer electrolytes

Ø Gullbrekken, SK Schnell - New Journal of Chemistry, 2023 - pubs.rsc.org
Understanding how microscopic mechanisms govern macroscopic transport properties is
important for development of improved electrolytes for Li-ion batteries. The archetypal …

Chain-like Structures Facilitate Li+ Transport in Concentrated Aqueous Electrolytes: Insights from Ultrafast Infrared Spectroscopy and Molecular Dynamics …

M Zhang, Y Gao, L Fu, Y Bai, S Mukherjee… - The Journal of …, 2023 - ACS Publications
Highly concentrated aqueous electrolytes have attracted attention due to their unique
applications in lithium ion batteries (LIBs). However, the solvation structure and transport …

On Relative Importance of Vehicular and Structural Motions in Defining Electrolyte Transport

A Mistry, Z Yu, L Cheng… - Journal of the …, 2023 - iopscience.iop.org
Molecular motions of ionic and neutral electrolyte species determine transport properties at
the continuum scale. These molecular motions can be classified as vehicular (eg, cations …

Revisiting Ultrafast Dynamics in Carbonate-Based Electrolytes for Li-Ion Batteries: Clarifying 2D-IR Cross-Peak Interpretation

C Lim, J Jeon, K Park, C Liang, Y Chae… - The Journal of …, 2023 - ACS Publications
Understanding chemical exchange in carbonate-based electrolytes employed in Li-ion
batteries (LIBs) is crucial for elucidating ion transport mechanisms. Ultrafast two-dimensional …

Ionic conduction mechanism in high concentration lithium ion electrolytes

X Chen, DG Kuroda - Chemical Communications, 2023 - pubs.rsc.org
The conduction mechanism of a family of high concentration lithium electrolytes (HCEs) is
investigated. It is found in all HCEs that the molecular motions are regulated by the anion …