London dispersion (LD) interactions are the main contribution of the attractive part of the van
der Waals potential. Even though LD effects are the driving force for molecular aggregation …

We suggest a scale of dispersion energy donors (DEDs) that allows for direct comparisons
with steric effects. This scale is based on the classic A-values and allows groups to reorient …

Halogen-powered static conversion batteries (HSCBs) thrive in energy storage applications.
They fall into the category of secondary non-flow batteries and operate by reversibly …

In this work, a noncoplanar terphenyl served as a building block to synthesize a novel 3, 3′‐
substituted bipyridyl ligand (L1) which further reacted with binuclear half‐sandwich units …

The packing of molecular crystals, in which the constituent molecular units have no
directional forces, is primarily controlled by weak London dispersion (LD) forces. These …

In Chemistry, complexity is not necessarily associated to large systems, as illustrated by the
textbook example of axial–equatorial equilibrium in mono-substituted cyclohexanes. The …

We define Δ G GA as the free energy change for the formal equilibrium:[13] GH+ 1-X-
adamantane→[13] GX+ adamantane, where [13] GH is the C13H22 fragment of all-trans …

A series of alkali metal 1‐adamantoxide (OAd1) complexes of formula [M (OAd1)(HOAd1) 2],
where M= Li, Na or K, were synthesised by reduction of 1‐adamantanol with excess of the …

Vicinal difluorides adopt defined conformations due to the electronic properties of fluorine.
Therefore, they could be valuable for controlling the constellation of functional groups about …

We have quantum chemically investigated the nature and stability of C–C and Si–Si bonds
in R3A–AR3 (A= C, Si; R3= H3, Me3, Me2Ph, MePh2, Ph3, t-Bu3) using density functional …