Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Conspectus Due to the rarity of precious metals like palladium, nickel catalysis is becoming
an increasingly important player in organic synthesis, especially for the formation of bonds …

Catalytic asymmetric methods for the synthesis of synthetically versatile P‐stereogenic
building blocks offer an efficient and practical approach for the diversity‐oriented …

A broadly improved second generation catalytic two‐phase strategy for the enantioselective
synthesis of stereogenic at phosphorus (V) compounds is described. This protocol …

Different from the reported work focusing on the construction of single P‐or C‐stereocenter
via hydrophosphinylation of unsaturated carbon bonds, the highly diastereo‐and …

P‐stereogenic phosphorus compounds are essential across various fields, yet their
synthesis via enantioselective P− C bond formation remains both challenging and …

Novel synthetic methods for P-chirogenic four-coordinate pentadentate organophosphorus
compounds are described. The synthetic pathways commenced with the use of phosphates …

Developing catalytic reactions using nonprecious-metal to achieve various synthetic
transformations remains a valuable pursuit to the scientific community. As part of a …

Phosphorus-containing unsaturated hydrocarbons, including alkenyl, allenyl, and alkynyl
phosphoryl compounds, constitute a significant subclass of organophosphorus …

For more than five decades, P‐stereogenic aminophosphine chalcogenides and boranes
have attracted scientific attention and are still in the focus of ongoing research. In the last …