Reactions of Na2PdCl4 with two equivalents of 2-aminopyridine (2-ampy), 2-
acetylaminopyridine (2-aampy) or 2-acetylaminopyrimidine (2-aampym) afford complexes of …

In this work we have studied the structure of silver (I) thiolate oligomers that lead to the
formation of argentophilic hydrogels. The results showed two different and clearly …

Palladium (II) and platinum (II) thiosaccharinate complexes [M (κ1-tsac) 2 {κ2-Ph2P (CH2)
nPPh2}](M= Pd, Pt; n= 1–4) have been prepared, palladium complexes from reaction of [Pd …

Abstract Reactions of [Pd (Me 2 NCH 2 C 6 H 4-κ 2 N, C)(μ-Cl)] 2 with two equivalents of
sodium saccharinate (Nasac), thiosaccharin (Htsac) or sodium benzisothiozolinate (Nabit) …

Abstract Reactions of [Ru 3 (CO) 12] with thiosaccharin (tsacH) at different temperatures
have been investigated. At 40° C, the diruthenium complex [Ru 2 (CO) 6 (μ-N, S-tsac) 2](1) is …

Treatment of Ag6 (tsac) 6 (tsac= thiosaccharinate anion) with pyridine (py) and 1, 10-
phenanthroline (o-phen) each affords two novel silver (I)-thiosaccharinate complexes …

Reactions of triosmium clusters bearing a bridging saccharinate (sac) or thiosaccharinate
(tsac) ligand with Ph 3 EH (E= Sn, Ge) are examined. The saccharinate cluster [HOs 3 (CO) …

Four new ternary complexes of copper (I) with thiosaccharin and phosphanes were
prepared. The reaction of [Cu4 (tsac) 4 (CH3CN) 2](1)(tsac: thiosaccharinate anion) with …

Three silver thiosaccharinate complexes, two of them with diverse coordination geometries
controlled by the ancillary nitrogen donor ligands are presented. The dinuclear silver …

The reaction of Ag6 (tsac) 6 (1)(tsac= thiosaccharinate anion) with triphenylphosphine gives
rise to the already reported [Ag (tsac)(PPh3) 3] complex (2) and to two new silver …