Peroxides form an important class of chemicals in which two oxygen atoms are linked
together by a single covalent bond (R− O− O− R, R= H, SO 3 K, alkyl, etc.), with a wide range …

In recent years, great improvements have been made on palladium‐catalyzed radical
reactions. Emerging elegant methodologies of radical involved palladium‐catalyzed …

A direct decarboxylative strategy for the generation of aza‐o‐quinone methides (aza‐o‐
QMs) by N‐heterocyclic carbene (NHC) catalysis has been discovered and explored. This …

Selective functionalization of highly inert and ubiquitous Csingle bondH bonds that would
provide a ready access to synthetically valuable motifs has perplexed the chemists since …

A Pd‐catalyzed novel and efficient protocol has been developed for the direct
functionalization of 2‐phenyl‐4H‐benzo [d][1, 3] oxazin‐4‐ones with α‐oxo carboxylic acids …

We herein report a practical and efficient transition metal-free cascade cyclization reaction of
2-acylbenzoic acids with various anthranilic acids and anthranilamides to furnish …

We herein report the acid/base-steered two distinct reaction pathways of 2-acylbenzoic
acids with isatoic anhydrides. In the presence of Na2CO3, the cascade process consists of …

A microwave assisted, palladium-catalyzed regioselective halogenation of 3-phenyl-2H-
benzo [b][1, 4] oxazin-2-ones has been demonstrated using inexpensive and readily …

Radical reactions have been a fascinating arena in organic chemistry for decades and the
rapid progress in this field is the topic of this review. Generation of radicals through …

This chapter reviews the advances on the Cu‐catalyzed asymmetric hydroboration of
Michael acceptors and the palladium‐catalyzed domino dehydrogenation/Heck‐type …