Diverse emission properties of transition metal complexes beyond exclusive single phosphorescence and their wide applications

K Li, Y Chen, J Wang, C Yang - Coordination Chemistry Reviews, 2021 - Elsevier
Luminescence properties and excited state reactivities of photoactive transition metal
complexes have been harnessed for various applications in the fields of electroluminescent …

Functional materials based on cyclometalated platinum (II) β-diketonate complexes: A Review of structure–property relationships and applications

A Haque, H El Moll, KM Alenezi, MS Khan, WY Wong - Materials, 2021 - mdpi.com
Square planar organoplatinum (II) complexes have garnered immense interest in the area of
materials research. The combination of the Pt (II) fragment with mono-, bi-tri-and tetradentate …

Extended ligand conjugation and dinuclearity as a route to efficient platinum-based near-infrared (NIR) triplet emitters and solution-processed NIR-OLEDs

MZ Shafikov, P Pander, AV Zaytsev… - Journal of Materials …, 2021 - pubs.rsc.org
Near infrared (NIR) emission from molecular materials is typically targeted by using more
extended conjugated systems compared to visible-emitting materials. But efficiencies …

Thermally activated delayed fluorescence from Ag (I) complexes: a route to 100% quantum yield at unprecedentedly short decay time

MZ Shafikov, AF Suleymanova, R Czerwieniec… - Inorganic …, 2017 - ACS Publications
The four new Ag (I) complexes Ag (phen)(P2-nCB)(1), Ag (idmp)(P2-nCB)(2), Ag (dmp)(P2-
nCB)(3), and Ag (dbp)(P2-nCB)(4) with P2-nCB= bis (diphenylphosphine)-nido-carborane …

Dinuclear design of a Pt (II) complex affording highly efficient red emission: photophysical properties and application in solution-processible OLEDs

MZ Shafikov, R Daniels, P Pander… - … applied materials & …, 2019 - ACS Publications
The light-emitting efficiency of luminescent materials is invariably compromised on moving
to the red and near-infrared regions of the spectrum due to the transfer of electronic excited …

Near infrared phosphorescent dinuclear Ir (III) complex exhibiting unusually slow intersystem crossing and dual emissive behavior

MZ Shafikov, AV Zaytsev… - The Journal of …, 2020 - ACS Publications
A dinuclear iridium (III) complex IrIr shows dual emission consisting of near infrared (NIR)
phosphorescence (λmax= 714 nm, CH2Cl2, T= 300 K) and green fluorescence (λmax= 537 …

Unusually fast phosphorescence from Ir (III) complexes via dinuclear molecular design

MZ Shafikov, R Daniels… - The Journal of Physical …, 2019 - ACS Publications
The design and detailed photophysical study of two novel Ir (III) complexes featuring mono-
and dinuclear design are presented. Emission quantum yield and decay times in solution …

Non-Stereogenic Dinuclear Ir (III) Complex with a Molecular Rack Design to Afford Efficient Thermally Enhanced Red Emission

MZ Shafikov, R Martinscroft, C Hodgson… - Inorganic …, 2021 - ACS Publications
Cyclometalated complexes containing two or more metal centers were recently shown to
offer photophysical properties that are advantageous compared to their mononuclear …

Excitation-Wavelength-Dependent and Auxiliary-Ligand-Tuned Intersystem-Crossing Efficiency in Cyclometalated Platinum (II) Complexes: Spectroscopic and …

K Li, GSM Tong, J Yuan, C Ma, L Du, C Yang… - Inorganic …, 2020 - ACS Publications
Understanding the factors affecting the intersystem-crossing (ISC) rate constant (k ISC) of
transition-metal complexes is crucial to material design with tailored photophysical …

Coumarin-pyridine push-pull fluorophores: Synthesis and photophysical studies

RF Fatykhov, AD Sharapov, ES Starnovskaya… - … Acta Part A: Molecular …, 2022 - Elsevier
A series of coumarin-pyridine-based push-pull fluorophores were prepared starting from 1,
2, 4-triazines by using direct CH functionalization (SN H-reaction)–Diels-Alder–retro Diels …