Recent advances in the chemistry of ketyl radicals
Ketyl radicals are valuable reactive intermediates for synthesis and are used extensively to
construct complex, functionalized products from carbonyl substrates. Single electron transfer …
construct complex, functionalized products from carbonyl substrates. Single electron transfer …
Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions
Y Tanabe, Y Nishibayashi - Chemical Society Reviews, 2021 - pubs.rsc.org
N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …
whereas biological nitrogen fixation is achieved under ambient conditions, which has …
Coordination-induced bond weakening
NG Boekell, RA Flowers - Chemical Reviews, 2022 - ACS Publications
Coordination-induced bond weakening is a phenomenon wherein ligand X–H bond
homolysis occurs in concert with the energetically favorable oxidation of a coordinating …
homolysis occurs in concert with the energetically favorable oxidation of a coordinating …
Radical cascade reactions triggered by single electron transfer
MP Plesniak, HM Huang, DJ Procter - Nature Reviews Chemistry, 2017 - nature.com
The rapid generation of molecular complexity from simple starting materials is of paramount
importance in synthetic chemistry. The unique combination of high reactivity and high …
importance in synthetic chemistry. The unique combination of high reactivity and high …
Ynamide Smiles rearrangement triggered by visible-light-mediated regioselective ketyl–ynamide coupling: rapid access to functionalized indoles and isoquinolines
ZS Wang, YB Chen, HW Zhang, Z Sun… - Journal of the …, 2020 - ACS Publications
In the past decades, significant advances have been made on radical Smiles
rearrangement. However, the eventually formed radical intermediates in these reactions are …
rearrangement. However, the eventually formed radical intermediates in these reactions are …
Radical carbonyl umpolung arylation via dual nickel catalysis
The formation of carbon–carbon bonds lies at the heart of synthetic organic chemistry and is
widely applied to construct complex drugs, polymers, and materials. Despite its importance …
widely applied to construct complex drugs, polymers, and materials. Despite its importance …
Reductive Cross‐Coupling of α‐Oxy Halides Enabled by Thermal Catalysis, Photocatalysis, Electrocatalysis, or Mechanochemistry
Herein, we report a reductive cross‐coupling reaction of α‐oxy halides, simply generated
from aldehydes, with a series of C (sp2)‐and C (sp)‐electrophiles. A wide range of aryl and …
from aldehydes, with a series of C (sp2)‐and C (sp)‐electrophiles. A wide range of aryl and …
Visible‐Light Photocatalysis of the Ketyl Radical Coupling Reaction
Q Xia, J Dong, H Song, Q Wang - Chemistry–A European …, 2019 - Wiley Online Library
Ketyl radical coupling reactions for the construction of diversely functionalized alcohols have
been continuously developed for many decades. Based on the recently widespread …
been continuously developed for many decades. Based on the recently widespread …
Catalytic Reductive N‐Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments
JR Cabrero‐Antonino, R Adam… - Angewandte Chemie …, 2019 - Wiley Online Library
N‐Alkylamines are key intermediates in the synthesis of fine chemicals, dyes, and natural
products, and hence are highly valuable building blocks in organic chemistry. Consequently …
products, and hence are highly valuable building blocks in organic chemistry. Consequently …
Making Full Use of TMSCF3: Deoxygenative Trifluoromethylation/Silylation of Amides
Y Wang, SJ Li, F Jiang, Y Lan… - Journal of the American …, 2024 - ACS Publications
As one of the most powerful trifluoromethylation reagents,(trifluoromethyl) trimethylsilane
(TMSCF3) has been widely used for the synthesis of fluorine-containing molecules …
(TMSCF3) has been widely used for the synthesis of fluorine-containing molecules …