Ketyl radicals are valuable reactive intermediates for synthesis and are used extensively to
construct complex, functionalized products from carbonyl substrates. Single electron transfer …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

Coordination-induced bond weakening is a phenomenon wherein ligand X–H bond
homolysis occurs in concert with the energetically favorable oxidation of a coordinating …

The rapid generation of molecular complexity from simple starting materials is of paramount
importance in synthetic chemistry. The unique combination of high reactivity and high …

In the past decades, significant advances have been made on radical Smiles
rearrangement. However, the eventually formed radical intermediates in these reactions are …

The formation of carbon–carbon bonds lies at the heart of synthetic organic chemistry and is
widely applied to construct complex drugs, polymers, and materials. Despite its importance …

Herein, we report a reductive cross‐coupling reaction of α‐oxy halides, simply generated
from aldehydes, with a series of C (sp2)‐and C (sp)‐electrophiles. A wide range of aryl and …

Ketyl radical coupling reactions for the construction of diversely functionalized alcohols have
been continuously developed for many decades. Based on the recently widespread …

N‐Alkylamines are key intermediates in the synthesis of fine chemicals, dyes, and natural
products, and hence are highly valuable building blocks in organic chemistry. Consequently …

As one of the most powerful trifluoromethylation reagents,(trifluoromethyl) trimethylsilane
(TMSCF3) has been widely used for the synthesis of fluorine-containing molecules …