Organic photoredox catalysis

NA Romero, DA Nicewicz - Chemical reviews, 2016 - ACS Publications
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic
transformations with a range of applications. This overview is arranged by catalyst class …

Mechanistic insight into the photoredox catalysis of anti-markovnikov alkene hydrofunctionalization reactions

NA Romero, DA Nicewicz - Journal of the American Chemical …, 2014 - ACS Publications
We describe our efforts to understand the key mechanistic aspects of the previously reported
alkene hydrofunctionalization reactions using 9-mesityl-10-methylacridinium (Mes-Acr+) as …

Electron‐Poor Acridones and Acridiniums as Super Photooxidants in Molecular Photoelectrochemistry by Unusual Mechanisms

J Žurauskas, S Boháčová, S Wu, V Butera… - Angewandte …, 2023 - Wiley Online Library
Electron‐deficient acridones and in situ generated acridinium salts are reported as potent,
closed‐shell photooxidants that undergo surprising mechanisms. When bridging acyclic …

N‐Substituted Acridinium as a Multi‐Responsive Recognition Unit in Supramolecular Chemistry

HP Jacquot de Rouville, J Hu, V Heitz - ChemPlusChem, 2021 - Wiley Online Library
The N‐substituted acridinium motif is an electron‐deficient unit with appealing multi‐
responsive properties which have been exploited in the field of supramolecular chemistry …

Photoacidic and photobasic behavior of transition metal compounds with carboxylic acid group (s)

RM O'Donnell, RN Sampaio, G Li… - Journal of the …, 2016 - ACS Publications
Excited state proton transfer studies of six Ru polypyridyl compounds with carboxylic
acid/carboxylate group (s) revealed that some were photoacids and some were photobases …

Novel Oxidative Ugi Reaction for the Synthesis of Highly Active, Visible‐Light, Imide‐Acridinium Organophotocatalysts

A Gini, M Uygur, T Rigotti, J Alemán… - … A European Journal, 2018 - Wiley Online Library
A newly designed class of acridinium‐based organophotocatalysts bearing an imide group
at the C9‐position is presented. To achieve these unprecedented structures, a synthetic …

Cationic and betaine-type boronated acridinium dyes: synthesis, characterization, and photocatalytic activity

K Durka, M Urban, M Dabrowski, P Jankowski, T Kliś… - ACS …, 2019 - ACS Publications
A series of isomeric boronated acridinium dyes were obtained by reactions of 10-(4′-
octyloxyphenyl) functionalized 9 (10 H)-acridanone derivative with lithiated phenylboronic …

Copper-Catalyzed N, N-Diarylation of Amides for the Construction of 9, 10-Dihydroacridine Structure and Applications in the Synthesis of Diverse Nitrogen-Embedded …

ML Tan, S Tong, SK Hou, J You, MX Wang - Organic Letters, 2020 - ACS Publications
We reported herein CuI/DMEDA catalyzed N, N-diarylation reaction of amides with various
di (o-bromoaryl) methanes to produce diverse 9, 10-dihydroacridine derivatives. The …

Toward organic photohydrides: Excited-state behavior of 10-methyl-9-phenyl-9, 10-dihydroacridine

X Yang, J Walpita, D Zhou, HL Luk, S Vyas… - The Journal of …, 2013 - ACS Publications
The excited-state hydride release from 10-methyl-9-phenyl-9, 10-dihydroacridine (PhAcrH)
was investigated using steady-state and time-resolved UV/vis absorption spectroscopy …

A long-lived fluorenyl cation: efficiency booster for uncaging and photobase properties

C Abdellaoui, V Hermanns, M Reinfelds… - Physical Chemistry …, 2022 - pubs.rsc.org
The photochemistry of fluorenols has been of special interest for many years. This is
because both the fluorenol and the fluorenyl cation are antiaromatic in the ground state due …