Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …
abundant transition metals due to their ready availability, economic advantage, and novel …
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions
Y Wang, M Wang, Y Li, Q Liu - Chem, 2021 - cell.com
The development of novel and efficient earth-abundant metal catalysts as inexpensive and
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …
Phosphine free Mn-complex catalysed dehydrogenative C–C and C–heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine …
Herein the first sustainable synthesis of quinoxalines, pyrazines and benzothiazoles
catalysed by a phosphine free Mn (I) complex via acceptorless dehydrogenative coupling …
catalysed by a phosphine free Mn (I) complex via acceptorless dehydrogenative coupling …
Phosphine‐free NNN‐manganese complex catalyzed α‐alkylation of ketones with primary alcohols and Friedländer quinoline synthesis
Herein, we report a very simple and inexpensive catalytic system based on Earth's abundant
transition metal manganese and on a bench‐stable phosphine‐free NNN‐pincer ligand for …
transition metal manganese and on a bench‐stable phosphine‐free NNN‐pincer ligand for …
Advancements in multifunctional manganese complexes for catalytic hydrogen transfer reactions
Catalytic hydrogen transfer reactions have enormous academic and industrial applications
for the production of diverse molecular scaffolds. Over the past few decades, precious late …
for the production of diverse molecular scaffolds. Over the past few decades, precious late …
Phosphine-Free Manganese Catalyst Enables Selective Transfer Hydrogenation of Nitriles to Primary and Secondary Amines Using Ammonia–Borane
Herein we report the synthesis of primary and secondary amines by nitrile hydrogenation,
employing a borrowing hydrogenation strategy. A class of phosphine-free manganese (I) …
employing a borrowing hydrogenation strategy. A class of phosphine-free manganese (I) …
Reversible interconversion between methanol-diamine and diamide for hydrogen storage based on manganese catalyzed (de) hydrogenation
Z Shao, Y Li, C Liu, W Ai, SP Luo, Q Liu - Nature communications, 2020 - nature.com
The development of cost-effective, sustainable, and efficient catalysts for liquid organic
hydrogen carrier systems is a significant goal. However, all the reported liquid organic …
hydrogen carrier systems is a significant goal. However, all the reported liquid organic …
Manganese catalyzed acceptorless dehydrogenative coupling reactions
Acceptorless dehydrogenative coupling (ADC) has emerged as a powerful tool in the
chemists' arsenal for the construction of various carbon‐carbon and carbon‐heteroatom …
chemists' arsenal for the construction of various carbon‐carbon and carbon‐heteroatom …
Manganese catalyzed α-alkylation of nitriles with primary alcohols
The manganese (I) complex bearing a bidentate hydrazone ligand efficiently catalyzes the α-
alkylations of nitrile using primary alcohols as alkylating agents. α-Functionalized nitriles …
alkylations of nitrile using primary alcohols as alkylating agents. α-Functionalized nitriles …
Manganese catalyzed α-methylation of ketones with methanol as a C1 source
A Bruneau-Voisine, L Pallova, S Bastin… - Chemical …, 2019 - pubs.rsc.org
The direct α-methylation of ketones with methanol under hydrogen borrowing conditions
using a well-defined manganese PN3P complex as a pre-catalyst was, for the first time …
using a well-defined manganese PN3P complex as a pre-catalyst was, for the first time …