Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Homogeneously catalyzed electroreduction of carbon dioxide—methods, mechanisms, and catalysts

R Francke, B Schille, M Roemelt - Chemical reviews, 2018 - ACS Publications
The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

Molecular polypyridine-based metal complexes as catalysts for the reduction of CO 2

N Elgrishi, MB Chambers, X Wang… - Chemical Society …, 2017 - pubs.rsc.org
Polypyridyl transition metal complexes represent one of the more thoroughly studied classes
of molecular catalysts towards CO2 reduction to date. Initial reports in the 1980s began with …

Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst

J Bonin, M Robert, M Routier - Journal of the American Chemical …, 2014 - ACS Publications
Converting CO2 into valuable compounds using sunlight as the energy input and an earth-
abundant metal complex as the catalyst is an exciting challenge related to contemporary …

Molecular catalysts for CO2 Electroreduction: Progress and prospects with pincer type complexes

HA Younus, N Ahmad, W Ni, X Wang, M Al-Abri… - Coordination Chemistry …, 2023 - Elsevier
Transforming wastes or hazardous materials into value-added chemical products is of great
concern from economic, environmental, and sustainable prospects. Various approaches …

Metal‐Terpyridine Complexes in Catalytic Application–A Spotlight on the Last Decade

A Winter, US Schubert - ChemCatChem, 2020 - Wiley Online Library
Abstract 2, 2′: 6′, 2′′‐Terpyridine (tpy) and its derivatives represent highly versatile
ligands for the complexation of transition metal ions. Today, such complexes are employed …

New Ru (II) photocages operative with near-IR light: new platform for drug delivery in the PDT window

MH Al-Afyouni, TN Rohrabaugh, KF Al-Afyouni… - Chemical …, 2018 - pubs.rsc.org
A series of Ru (II) complexes bearing the tridentate 2, 6-di (quinolin-2-yl) pyridine (dqpy)
ligand were designed to undergo photoinduced ligand dissociation with red/near-IR light …

Exploiting consecutive photoinduced electron transfer (ConPET) in CO 2 photoreduction

Y Fang, T Liu, L Chen, D Chao - Chemical Communications, 2022 - pubs.rsc.org
The consecutive photoinduced electron transfer (ConPET) process of 1, 2, 3, 5-Tetrakis
(carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) in CO2 photoreduction to achieve powerful …

Toward “metalloMOFzymes”: Metal–Organic Frameworks with Single-Site Metal Catalysts for Small-Molecule Transformations

SM Cohen, Z Zhang, JA Boissonnault - Inorganic Chemistry, 2016 - ACS Publications
Metal–organic frameworks (MOFs) are being increasingly studied as scaffolds and supports
for catalysis. The solid-state structures of MOFs, combined with their high porosity, suggest …

Activating a Low Overpotential CO2 Reduction Mechanism by a Strategic Ligand Modification on a Ruthenium Polypyridyl Catalyst

BA Johnson, S Maji, H Agarwala… - Angewandte Chemie …, 2016 - Wiley Online Library
The introduction of a simple methyl substituent on the bipyridine ligand of [Ru
(tBu3tpy)(bpy)(NCCH3)] 2+(tBu3tpy= 4, 4′, 4′′‐tri‐tert‐butyl‐2, 2′: 6′, 2 …