Electrochemistry of corroles in nonaqueous media
This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …
1980 until the present. The outline of the review is grouped according to the periodic table …
Synthesis, characterization, and reactivities of high valent metal–corrole (M= Cr, Mn, and Fe) complexes
For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …
relatively lower. However, biological systems in various enzymatic reactions rely extensively …
Valence tautomerism in a high-valent manganese–oxo porphyrinoid complex induced by a lewis acid
P Leeladee, RA Baglia, KA Prokop… - Journal of the …, 2012 - ACS Publications
Addition of the Lewis acid Zn2+ to (TBP8Cz) MnV (O) induces valence tautomerization,
resulting in the formation of [(TBP8Cz+•) MnIV (O)–Zn2+]. This new species was …
resulting in the formation of [(TBP8Cz+•) MnIV (O)–Zn2+]. This new species was …
The corrole radical
P Schweyen, K Brandhorst, R Wicht… - Angewandte …, 2015 - Wiley Online Library
Abstract The reaction of 5, 10, 15‐trimesitylcorrole (H3cor) with tungsten hexachloride and
tungsten hexacarbonyl resulted in the unexpected formation of the 3, 17‐dichloro‐5, 10, 15 …
tungsten hexacarbonyl resulted in the unexpected formation of the 3, 17‐dichloro‐5, 10, 15 …
Generation of an Isolable, Monomeric Manganese(V)–Oxo Complex from O2 and Visible Light
KA Prokop, DP Goldberg - Journal of the American Chemical …, 2012 - ACS Publications
The direct conversion of a MnIII complex [(TBP8Cz) MnIII (1)] to a MnV–oxo complex
[(TBP8Cz) MnV (O)(2)] with O2 and visible light is reported. Complex 1 is also shown to …
[(TBP8Cz) MnV (O)(2)] with O2 and visible light is reported. Complex 1 is also shown to …
Photophysical properties of β-substituted free-base corroles
Corroles are an emergent class of fluorophores that are finding an application and reaction
chemistry to rival their porphyrin analogues. Despite a growing interest in the synthesis …
chemistry to rival their porphyrin analogues. Despite a growing interest in the synthesis …
Mn (V)(O) versus Cr (V)(O) porphyrinoid complexes: Structural characterization and implications for basicity controlling H-atom abstraction
Isomorphous crystals of MnV (O) and CrV (O) corrolazines were characterized by single
crystal X-ray diffraction. Reactivity studies with H atom donors and separated PCET reagents …
crystal X-ray diffraction. Reactivity studies with H atom donors and separated PCET reagents …
Molecular structures of free-base corroles: nonplanarity, chirality, and enantiomerization
The molecular structures of free-base corroles are illustrative of a variety of bonded and
nonbonded interactions including aromaticity, intra-as well as intermolecular hydrogen …
nonbonded interactions including aromaticity, intra-as well as intermolecular hydrogen …
Photochemical oxidation of a manganese (III) complex with oxygen and toluene derivatives to form a manganese (V)-oxo complex
Visible light photoirradiation of an oxygen-saturated benzonitrile solution of a manganese
(III) corrolazine complex [(TBP8Cz) MnIII](1):[TBP8Cz= octakis (p-tert-butylphenyl) …
(III) corrolazine complex [(TBP8Cz) MnIII](1):[TBP8Cz= octakis (p-tert-butylphenyl) …
5d early-transition-metal corroles: a trioxo-bridged binuclear tungsten (VI) derivative
I Nigel-Etinger, I Goldberg, Z Gross - Inorganic chemistry, 2012 - ACS Publications
5d Early-Transition-Metal Corroles: a Trioxo-Bridged Binuclear Tungsten(VI) Derivative |
Inorganic Chemistry ACS ACS Publications C&EN CAS Find my institution Log In Inorganic …
Inorganic Chemistry ACS ACS Publications C&EN CAS Find my institution Log In Inorganic …