Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery

C Shen, Y Li, Y Xu, C Wang, Q Liu - Green Chemistry, 2022 - pubs.rsc.org
Biomass conversion to platform chemicals, value-added chemicals, or fuels is important
because it provides a sustainable or carbon-neutral alternative to fossil fuel feedstocks …

Sustainable synthesis of drop-in chemicals from biomass via chemical catalysis: Scopes, challenges, and the way forward

S Dutta - Energy & Fuels, 2023 - ACS Publications
A handful of small organics, namely, ethylene, propylene, butadiene, benzene, toluene,
xylenes, and methanol, produced from petroleum and other fossilized carbon-based …

Accelerating manufacturing for biomass conversion via integrated process and bench digitalization: a perspective

SP Batchu, B Hernandez, A Malhotra, H Fang… - Reaction Chemistry & …, 2022 - pubs.rsc.org
We present a perspective for accelerating biomass manufacturing via digitalization. We
summarize the challenges for manufacturing and identify areas where digitalization can …

A perspective on catalytic production of olefinic compounds from biomass

Y Nakagawa, M Yabushita, K Tomishige - RSC Sustainability, 2023 - pubs.rsc.org
Chemical syntheses of industrially important olefins and unsaturated oxygenates from
biomass are reviewed. Their syntheses are discussed in two aspects: common key reactions …

Synthesis of high-surface area tungstated zirconia by atomic layer deposition on mesoporous silica

CY Wang, O Kwon, RJ Gorte, JM Vohs - Microporous and Mesoporous …, 2022 - Elsevier
Atomic layer deposition (ALD) was used to prepare ZrO 2 films on the surface of the
mesoporous silica, SBA-15, and to modify the surface of these films with WO 3 in order to …

Furfural upgrading by aldol condensation with ketones over solid-base catalysts

R Huang, J Chang, H Choi, JM Vohs, RJ Gorte - Catalysis Letters, 2022 - Springer
Aldol condensation reactions between furfural and various ketones were studied in a flow
reactor at 373 K and 100 psi for application to upgrading of furfural. Specific rates for the …

Catalytic isomerization of dihydroxyacetone to lactic acid by heat treated zeolites

MA Hossain, KN Mills, AM Molley, MS Rahaman… - Applied Catalysis A …, 2021 - Elsevier
Lactic acid can be prepared by isomerization of renewable dihydroxyacetone over acid
catalysts. However, the activities of Lewis acid and Brønsted acid sites in dihydroxyacetone …

A Career in Catalysis: Raymond J. Gorte

OA Abdelrahman, EI Altman, M Cargnello… - ACS …, 2024 - ACS Publications
Ray Gorte has made major contributions to catalysis science and engineering in several
fields throughout his more than 40 years career spanning surface science, solid acids, fuel …

Cooperative Adsorption: Solvating the Hofmann Elimination of Alkylamines

H Chen, OA Abdelrahman - ACS Catalysis, 2021 - ACS Publications
A kinetic investigation of the vapor-phase Hofmann elimination of tert-butylamine (TBA) over
H-ZSM-5 reveals a carbocation-mediated E1-like mechanism, where isobutene and …

Sulfurous zeosils for dehydra-decyclization of tetrahydrofuran to renewable butadiene

RCA Ela, J Barroso, G Kumar, K Gawande… - Green …, 2024 - pubs.rsc.org
Renewable 1, 3-butadiene (1, 3-BD, C4H6) was synthesized from the tandem decyclization
and dehydration of biomass-derived tetrahydrofuran (THF) on weak Brønsted acid zeolite …