The transition metal-catalysed hydroboration reaction
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …
organic molecules was initially realised several decades ago. Although this area of …
First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
Recent advances in asymmetric borylation by transition metal catalysis
J Hu, M Ferger, Z Shi, TB Marder - Chemical Society Reviews, 2021 - pubs.rsc.org
Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …
development of materials science and pharmaceuticals. Much effort has been devoted to …
Photoinduced borylation for the synthesis of organoboron compounds: focus review
YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …
transformations. The development of practical and convenient ways to synthesize boronate …
Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
JV Obligacion, PJ Chirik - Nature Reviews Chemistry, 2018 - nature.com
The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …
established method for incorporating silane or borane groups, respectively, into …
Stereodivergent catalysis
IP Beletskaya, C Najera, M Yus - Chemical reviews, 2018 - ACS Publications
This review covers diastereo-and enantiodivergent catalyzed reactions in acyclic and cyclic
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …
C− H activation for the construction of C− B bonds
IAI Mkhalid, JH Barnard, TB Marder, JM Murphy… - Chemical …, 2010 - ACS Publications
A long-standing challenge in synthetic chemistry is the direct, selective functionalization of
alkyl, alkenyl, and aryl CH bonds. Much research has been devoted to the selective …
alkyl, alkenyl, and aryl CH bonds. Much research has been devoted to the selective …
The hidden role of boranes and borohydrides in hydroboration catalysis
AD Bage, K Nicholson, TA Hunt, T Langer… - ACS …, 2020 - ACS Publications
The continued development of hydroboration catalysts typifies the importance of this
transformation as a testbed for catalytic activity and as a fundamental reaction for organic …
transformation as a testbed for catalytic activity and as a fundamental reaction for organic …
Recent advances in the catalytic hydroboration of carbonyl compounds
ML Shegavi, SK Bose - Catalysis Science & Technology, 2019 - pubs.rsc.org
The chemoselective catalytic hydroboration of aldehydes and ketones has found
widespread applications in organic chemistry due to the synthetic utility of borate ester …
widespread applications in organic chemistry due to the synthetic utility of borate ester …
Alkylboronic esters from copper‐catalyzed borylation of primary and secondary alkyl halides and pseudohalides
CT Yang, ZQ Zhang, H Tajuddin, CC Wu… - Angewandte …, 2012 - Wiley Online Library
Alkylboronic acid derivatives are interesting compounds in medicinal chemistry (eg,
bortezomib).[1] They are more often used as synthetic intermediates for transition …
bortezomib).[1] They are more often used as synthetic intermediates for transition …