The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Dimers are probably the simplest model to facilitate the understanding of fundamental
physical and chemical processes that take place in much-expanded systems like …

Many kinds of radicals are stable enough to isolate, handle, and store without any special
precautions. The diversity in molecular architectures of these stable radicals is sufficiently …

Biradicals are molecules consisting of two unpaired electrons in two nearly degenerate non-
bonding molecular orbitals (NBMOs). They play a central role in bond breaking and …

The nature of the chemical bond is fundamental to the modern concept of chemistry. Species
that exhibit unusual interactions provide a valuable challenge to current theoretical models …

Owing to their switchable spin states and dynamic electronic character, organic-based
radical species have been invoked in phenomena unique to a variety of fields. When …

Rotational motions of ferrocene-based carousels have been achieved by electron transfer
centered on π-dimerizable 4, 4′-bipyridinium substituents introduced on both …

We describe our activities on radical-based compounds developed within the 6-year priority
program of the DFG Schwerpunktprogramm “Molekularer Magnetismus”. During this period …

Spin–Spin interactions between unpaired electrons in organic radicals are of utter
importance from the viewpoint of molecular magnetism and the development of smart …

Reviews Page 1 Russian Chemical Bulletin, International Edition, Vol. 69, No. 7, pp. 1203—1222,
July, 2020 1203 Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No …