Synthetic organic chemists have scoured the depths and breadth of the periodic table in
search of novel, unique, and efficient methods to assemble small molecules. Metal …

The reaction of zirconium metallacycles is used to produce a variety of main group
heterocycles including borole Diels-Alder dimers, gallóles, indacyclopentadienes, siloles …

Dialkylzirconocenes in situ generated such as Cp 2 Zr (n-Bu) 2, Cp 2 ZrEt 2, and Cp 2 Zr (t-
Bu)(i-Bu) are thermolyzed to afford zirconocene-alkene complexes. In the cases of Cp 2 Zr …

Reductive Cyclization of Enones by a Titanium Catalyst Page 1 J. Am. Chem.Soc. 1995, 117,
6785-6786 6785 Reductive Cyclization of Enones by a Titanium Catalyst Natasha M. Kablaoui …

In the presence of a catalytic amount of ruthenium (II) complexes,[RuCl2 (cod)] n, RuCl2
(cod)(MeCN) 2,[RuCl2 (nbd)] n,[RuCl2 (CO) 3] 2, and Cp* Ru (cod) Cl, 1, 6-dienes were …

Abstract η 2-Imine complexes of zirconium, or zirconaaziridines, have attracted attention as
amino carbanion equivalents. They can be prepared from an amine via C–H activation …

Cleavage of the aldehyde C= O bond takes place in the zirconocene‐and AlCl3‐mediated
cyclization of two molecules of an alkyne with an aldehyde to afford cyclopentadiene …

An effective protocol in which bis (trimethylphosphine) titanocene is used to catalyze the
reductive cyclization of enones to cyclopentanols via a metallacyclic intermediate has been …

The reaction of 1, 4-diazadienes RN CHCH NR with the titanocene and zirconocene
complexes of bis (trimethylsilyl) acetylene Cp2M (L)(η2-Me3SiC2SiMe3)(M= Ti, without L …

-19 J Kr1 mol-1 for the elimination of methane. A cyclometalation involving deprotonation a
to nitrogen by (R4)-best fits the data. The relationship between the rate of the reaction and …