Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

Recent years have seen rapid advances in the chemistry of small molecules containing
electron‐precise boron–boron bonds. This Review provides an overview of the latest …

Hexafluoroisopropanol (HFIP) is a solvent with unique properties that has recently gained
attention for promoting a wide range of challenging chemical reactions. It was initially …

We report a light-driven method for the intermolecular anti-Markovnikov hydroamination of
alkenes with primary heteroaryl amines. In this protocol, electron transfer between an amine …

Aminium radical cations have been extensively studied as electrophilic aminating species
that readily participate in C–N bond forming processes with alkenes and arenes. However …

Hydroaminoalkylation is a powerful, atom-economic catalytic reaction for the reaction of
amines with alkenes and alkynes. This C–H functionalization reaction allows for the atom …

We report here a photocatalytic method for the intermolecular anti-Markovnikov
hydroamination of unactivated olefins with primary alkyl amines to selectively furnish …

This review highlights the hydroelementation reactions of conjugated and separated diynes,
which depending on the process conditions, catalytic system, as well as the type of reagents …

Aniline derivatives are frequently encountered in molecules of industrial relevance such as
dyes or antioxidants, which make the development of synthetic methods for the …

This review provides an overview of synthetic transformations that have been performed by
both electro-and photoredox catalysis. Both toolboxes are evaluated and compared in their …