Multicharged cyclodextrin supramolecular assemblies

Z Liu, Y Liu - Chemical Society Reviews, 2022 - pubs.rsc.org
Multicharged cyclodextrin (CD) supramolecular assemblies, including those based on
positively/negatively charged modified mono-6-deoxy-CDs, per-6-deoxy-CDs, and random …

Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical nanomaterials

JM Cameron, G Guillemot, T Galambos… - Chemical Society …, 2022 - pubs.rsc.org
This review provides a comprehensive overview of recent advances in the supramolecular
organisation and hierarchical self-assembly of organo-functionalised hybrid …

Polyoxometalate‐Cyclodextrin‐Based Cluster‐Organic Supramolecular Framework for Polysulfide Conversion and Guest–Host Recognition in Lithium‐sulfur Batteries

L Ni, J Gu, X Jiang, H Xu, Z Wu, Y Wu, Y Liu… - Angewandte …, 2023 - Wiley Online Library
Developing polyoxometalate‐cyclodextrin cluster‐organic supramolecular framework (POM‐
CD‐COSF) still remains challenging due to an extremely difficult task in rationally …

Guided synthesis of a Mo/Zn dual single‐atom nanozyme with synergistic effect and peroxidase‐like activity

CB Ma, Y Xu, L Wu, Q Wang, JJ Zheng… - Angewandte Chemie …, 2022 - Wiley Online Library
We present a facile route towards a dual single‐atom nanozyme composed of Zn and Mo,
which utilizes the non‐covalent nano‐assembly of polyoxometalates, supramolecular …

Multicomponent Self‐Assembly of a Giant Heterometallic Polyoxotungstate Supercluster with Antitumor Activity

JC Liu, JF Wang, Q Han, P Shangguan… - Angewandte …, 2021 - Wiley Online Library
The hierarchical aggregation of molecular nanostructures from multiple components is a
grand synthetic challenge, which requires highly selective linkage control. We demonstrate …

Beyond charge balance: counter‐cations in polyoxometalate chemistry

A Misra, K Kozma, C Streb… - Angewandte Chemie …, 2020 - Wiley Online Library
Polyoxometalates (POMs) are molecular metal‐oxide anions applied in energy conversion
and storage, manipulation of biomolecules, catalysis, as well as materials design and …

The chaotropic effect as an assembly motif in chemistry

KI Assaf, WM Nau - Angewandte Chemie International Edition, 2018 - Wiley Online Library
Following up on scattered reports on interactions of conventional chaotropic ions (for
example, I−, SCN−, ClO4−) with macrocyclic host molecules, biomolecules, and …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Molecularly Engineered Room-Temperature Phosphorescence for Biomedical Application: From the Visible toward Second Near-Infrared Window

B Chang, J Chen, J Bao, T Sun, Z Cheng - Chemical Reviews, 2023 - ACS Publications
Phosphorescence, characterized by luminescent lifetimes significantly longer than that of
biological autofluorescence under ambient environment, is of great value for biomedical …

Interactions of native cyclodextrins with metal ions and inorganic nanoparticles: fertile landscape for chemistry and materials science

D Prochowicz, A Kornowicz, J Lewiński - Chemical reviews, 2017 - ACS Publications
Readily available cyclodextrins (CDs) with an inherent hydrophobic internal cavity and
hydrophilic external surface are macrocyclic entities that display a combination of molecular …