Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy
A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …
surfaces or deposited metal particles, to improve the understanding of their surface …
Infrared multiphoton dissociation spectroscopy with free‐electron lasers: On the road from small molecules to biomolecules
L Jašíková, J Roithová - Chemistry–A European Journal, 2018 - Wiley Online Library
Infrared multiphoton dissociation (IRMPD) spectroscopy is commonly used to determine the
structure of isolated, mass‐selected ions in the gas phase. This method has been widely …
structure of isolated, mass‐selected ions in the gas phase. This method has been widely …
Cryogenic ion trap vibrational spectroscopy of hydrogen-bonded clusters relevant to atmospheric chemistry
Recent advances in the gas phase vibrational spectroscopy of mass-selected ions are
described, highlighting experiments on hydrogen-bonded (HBed) clusters relevant to …
described, highlighting experiments on hydrogen-bonded (HBed) clusters relevant to …
Identification of active sites and structural characterization of reactive ionic intermediates by cryogenic ion trap vibrational spectroscopy
Cryogenic ion trap vibrational spectroscopy paired with quantum chemistry currently
represents the most generally applicable approach for the structural investigation of …
represents the most generally applicable approach for the structural investigation of …
Doping effects in cluster‐mediated bond activation
H Schwarz - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Gas‐phase investigations of judiciously doped oxide clusters permit to address fundamental
challenges related to, for example, the low‐temperature oxidation of CO or the selective …
challenges related to, for example, the low‐temperature oxidation of CO or the selective …
Selective C− H bond cleavage in methane by small gold clusters
SM Lang, TM Bernhardt, V Chernyy… - Angewandte …, 2017 - Wiley Online Library
Methane represents the major constituent of natural gas. It is primarily used only as a source
of energy by means of combustion, but could also serve as an abundant hydrocarbon …
of energy by means of combustion, but could also serve as an abundant hydrocarbon …
Thermal Reactions of (V2O5)nO– (n = 1–3) Cluster Anions with Ethylene and Propylene: Oxygen Atom Transfer Versus Molecular Association
Z Yuan, ZY Li, ZX Zhou, QY Liu… - The Journal of Physical …, 2014 - ACS Publications
Vanadium oxide cluster ions are prepared by laser ablation and the (V2O5) n O–(n= 1–3)
clusters (V2O6–, V4O11–, and V6O16–) are selected by a quadrupole mass filter and …
clusters (V2O6–, V4O11–, and V6O16–) are selected by a quadrupole mass filter and …
CO oxidation promoted by gold atoms supported on titanium oxide cluster anions
XN Li, Z Yuan, SG He - Journal of the American Chemical Society, 2014 - ACS Publications
Laser ablation generated Au x (TiO2) y O z–(x= 0, 1; y= 2, 3; z= 1, 2) oxide cluster anions
have been mass-selected using a quadrupole mass filter and reacted with CO in a hexapole …
have been mass-selected using a quadrupole mass filter and reacted with CO in a hexapole …
Slow photoelectron velocity-map imaging of cryogenically cooled anions
ML Weichman, DM Neumark - Annual review of physical …, 2018 - annualreviews.org
Slow photoelectron velocity-map imaging spectroscopy of cryogenically cooled anions (cryo-
SEVI) is a powerful technique for elucidating the vibrational and electronic structure of …
SEVI) is a powerful technique for elucidating the vibrational and electronic structure of …
Reactions of V4O10+ cluster ions with simple inorganic and organic molecules
Z Yuan, YX Zhao, XN Li, SG He - International Journal of Mass …, 2013 - Elsevier
The reactivity of mass-selected V 4 O 10+ cluster ions toward hydrocarbon molecules
including CH 4, C 2 H 4, and C 2 H 6 was explored in the references case by case. Herein …
including CH 4, C 2 H 4, and C 2 H 6 was explored in the references case by case. Herein …