Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy

A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …

Infrared multiphoton dissociation spectroscopy with free‐electron lasers: On the road from small molecules to biomolecules

L Jašíková, J Roithová - Chemistry–A European Journal, 2018 - Wiley Online Library
Infrared multiphoton dissociation (IRMPD) spectroscopy is commonly used to determine the
structure of isolated, mass‐selected ions in the gas phase. This method has been widely …

Cryogenic ion trap vibrational spectroscopy of hydrogen-bonded clusters relevant to atmospheric chemistry

N Heine, KR Asmis - International Reviews in Physical Chemistry, 2015 - Taylor & Francis
Recent advances in the gas phase vibrational spectroscopy of mass-selected ions are
described, highlighting experiments on hydrogen-bonded (HBed) clusters relevant to …

Identification of active sites and structural characterization of reactive ionic intermediates by cryogenic ion trap vibrational spectroscopy

H Schwarz, KR Asmis - Chemistry–A European Journal, 2019 - Wiley Online Library
Cryogenic ion trap vibrational spectroscopy paired with quantum chemistry currently
represents the most generally applicable approach for the structural investigation of …

Doping effects in cluster‐mediated bond activation

H Schwarz - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Gas‐phase investigations of judiciously doped oxide clusters permit to address fundamental
challenges related to, for example, the low‐temperature oxidation of CO or the selective …

Selective C− H bond cleavage in methane by small gold clusters

SM Lang, TM Bernhardt, V Chernyy… - Angewandte …, 2017 - Wiley Online Library
Methane represents the major constituent of natural gas. It is primarily used only as a source
of energy by means of combustion, but could also serve as an abundant hydrocarbon …

Thermal Reactions of (V2O5)nO (n = 1–3) Cluster Anions with Ethylene and Propylene: Oxygen Atom Transfer Versus Molecular Association

Z Yuan, ZY Li, ZX Zhou, QY Liu… - The Journal of Physical …, 2014 - ACS Publications
Vanadium oxide cluster ions are prepared by laser ablation and the (V2O5) n O–(n= 1–3)
clusters (V2O6–, V4O11–, and V6O16–) are selected by a quadrupole mass filter and …

CO oxidation promoted by gold atoms supported on titanium oxide cluster anions

XN Li, Z Yuan, SG He - Journal of the American Chemical Society, 2014 - ACS Publications
Laser ablation generated Au x (TiO2) y O z–(x= 0, 1; y= 2, 3; z= 1, 2) oxide cluster anions
have been mass-selected using a quadrupole mass filter and reacted with CO in a hexapole …

Slow photoelectron velocity-map imaging of cryogenically cooled anions

ML Weichman, DM Neumark - Annual review of physical …, 2018 - annualreviews.org
Slow photoelectron velocity-map imaging spectroscopy of cryogenically cooled anions (cryo-
SEVI) is a powerful technique for elucidating the vibrational and electronic structure of …

Reactions of V4O10+ cluster ions with simple inorganic and organic molecules

Z Yuan, YX Zhao, XN Li, SG He - International Journal of Mass …, 2013 - Elsevier
The reactivity of mass-selected V 4 O 10+ cluster ions toward hydrocarbon molecules
including CH 4, C 2 H 4, and C 2 H 6 was explored in the references case by case. Herein …