Atomically precise metal nanoclusters as catalysts for electrocatalytic CO 2 reduction

T Kawawaki, T Okada, D Hirayama, Y Negishi - Green Chemistry, 2024 - pubs.rsc.org
Electrochemical carbon dioxide (CO2) reduction can be used to convert CO2 into various
compounds at room temperature and ambient pressure using electricity generated from …

Advancing electrochemical CO2 reduction with group 11 metal nanoclusters for renewable energy solutions

S Biswas, Y Shingyouchi, M Ogami, M Kamiyama… - EcoEnergy, 2024 - Wiley Online Library
Understanding the intricate relationship between structure and properties is paramount in
distinguishing nanocluster (NC) materials from their counterparts. Despite the progress in …

Nanocluster Surface Microenvironment Modulates Electrocatalytic CO2 Reduction

S Yoo, S Yoo, G Deng, F Sun, K Lee, H Jang… - Advanced …, 2024 - Wiley Online Library
The catalytic activity and product selectivity of the electrochemical CO2 reduction reaction
(eCO2RR) depend strongly on the local microenvironment of mass diffusion at the …

Bulky ligands induce rich uncoordinated sites for boosting metal nanocluster catalysis

H Guo, Y Chen, YZ Han, Q Wu, L Wang, Q Xu… - Chemistry of …, 2024 - ACS Publications
The catalytic activity of ligand-protected metal nanoclusters is often hindered by the blocking
effect of surface ligands, necessitating the creation of more uncoordinated sites to enhance …

Carboxylate-Protected “Isostructural” Cu20 Nanoclusters as a Model System: Carboxylate Effect on Controlling Catalysis

B Yan, X You, X Tang, J Sun, Q Xu, L Wang… - Chemistry of …, 2024 - ACS Publications
Several recent studies have demonstrated the great promise of ligand-protected atomically
precise copper nanoclusters in driving various chemical transformation processes. The …

Thiacalix[4]arene Etching of an Anisotropic Cu70H22 Intermediate for Accessing Robust Modularly Assembled Copper Nanoclusters

HN Qin, MW He, J Wang, HY Li, ZY Wang… - Journal of the …, 2024 - ACS Publications
Atom-precise metal nanoclusters (NCs) with large bulk (nuclearity> 60) are important
species for insight into the embryonic phase of metal nanoparticles and their top-down …

Promoting CO2 Electroreduction to Hydrocarbon Products via Sulfur‐Enhanced Proton Feeding in Atomically Precise Thiolate‐Protected Cu Clusters

JK Li, JP Dong, SS Liu, Y Hua, XL Zhao… - Angewandte Chemie …, 2024 - Wiley Online Library
Thiolate‐protected Cu clusters with well‐defined structures and stable low‐coordinated Cu+
species exhibit remarkable potential for the CO2RR and are ideal model catalysts for …

Hydride-doped Ag17Cu10 nanoclusters as high-performance electrocatalysts for CO2 reduction

X Sun, P Wang, X Yan, H Guo, L Wang, Q Xu, B Yan… - Iscience, 2023 - cell.com
The atomically precise metal electrocatalysts for driving CO 2 reduction reactions are
eagerly pursued as they are model systems to identify the active sites, understand the …

State of Play of Critical Mineral Based Catalysts for Electrochemical E‐Refinery to Synthetic Fuels

P Ramadhany, Q Luong, Z Zhang, J Leverett… - Advanced …, 2024 - Wiley Online Library
The pursuit of decarbonization involves leveraging waste CO2 for the production of valuable
fuels and chemicals (eg, ethanol, ethylene, and urea) through the electrochemical CO2 …

[HTML][HTML] An empirical approach-based analysis for the exploration of ternary metal sulfide as an active and selective CO2 reduction electrocatalyst

AN El Aisnada, Y Yui, JE Lee, N Kitadai… - Materials Science and …, 2024 - Elsevier
In the quest for sustainable electrochemical carbon dioxide reduction reaction (CO 2 RR)
strategies, developing efficient and selective electrocatalysts remains a paramount …