Continuous Flow Upgrading of Selected C2–C6 Platform Chemicals Derived from Biomass

R Gerardy, DP Debecker, J Estager, P Luis… - Chemical …, 2020 - ACS Publications
The ever increasing industrial production of commodity and specialty chemicals inexorably
depletes the finite primary fossil resources available on Earth. The forecast of population …

Continuous reactions in supercritical carbon dioxide: problems, solutions and possible ways forward

X Han, M Poliakoff - Chemical Society Reviews, 2012 - pubs.rsc.org
This Tutorial Review focuses on supercritical carbon dioxide (scCO2), and discusses some
of the problems that have frustrated its wide use on an industrial scale. It gives some recent …

Continuous flow organic synthesis under high‐temperature/pressure conditions

T Razzaq, CO Kappe - Chemistry–An Asian Journal, 2010 - Wiley Online Library
Microreactor technology and continuous flow processing in general are key features in
making organic synthesis both more economical and environmentally friendly. When …

Self‐optimizing continuous reactions in supercritical carbon dioxide

AJ Parrott, RA Bourne, GR Akien, DJ Irvine… - Angewandte …, 2011 - infona.pl
Vollautomatisch: Mit einer Kombination aus automatisiertem Flussreaktor, Online‐Analyse
und Steuerungsalgorithmus (siehe schematischen Aufbau) gelingt die effiziente …

A critical look at reactions in class I and II gas-expanded liquids using CO2 and other gases

GR Akien, M Poliakoff - Green Chemistry, 2009 - pubs.rsc.org
A critical look at reactions in class I and II gas-expanded liquids using CO2 and other gases -
Green Chemistry (RSC Publishing) DOI:10.1039/B904097H Royal Society of Chemistry View …

Direct synthesis of dimethyl carbonate with supercritical carbon dioxide: characterization of a key organotin oxide intermediate

D Ballivet-Tkatchenko, S Chambrey, R Keiski… - Catalysis Today, 2006 - Elsevier
The direct synthesis of dimethyl carbonate (DMC) using carbon dioxide as solvent and
reagent for its fixation to methanol was explored with di-n-butyldimethoxystannane in order …

Remote-controlled experiments with cloud chemistry

RA Skilton, RA Bourne, Z Amara, R Horvath, J Jin… - Nature …, 2015 - nature.com
Developing cleaner chemical processes often involves sophisticated flow-chemistry
equipment that is not available in many economically developing countries. For reactions …

Continuous synthesis of glycerol acetates in supercritical carbon dioxide using Amberlyst 15®

M Rezayat, HS Ghaziaskar - Green Chemistry, 2009 - pubs.rsc.org
Continuous esterification of glycerol with acetic acid was investigated in supercritical carbon
dioxide (scCO2) using Amberlyst 15® as a heterogeneous catalyst. The effect of pressure at …

Effect of CO 2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1, 2-propanediol in water

S Wu, H Fan, Y Xie, Y Cheng, Q Wang, Z Zhang… - Green …, 2010 - pubs.rsc.org
The CO2–water system has the potential to serve as a substitute for mineral acids for some
reactions in acidic media. In this work, two reactions under hydrothermal conditions with and …

Phase Boundaries of CO2 + Toluene, CO2 + Acetone, and CO2 + Ethanol at High Temperatures and High Pressures

W Wu, J Ke, M Poliakoff - Journal of Chemical & Engineering Data, 2006 - ACS Publications
The phase boundaries of the CO2+ toluene, CO2+ acetone, and CO2+ ethanol binary
systems have been measured via a dynamic synthetic method based on a fiber optic …