This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

A nanographene-fused expanded carbaporphyrin (5) and its BF2 complex (6) were
synthesized. Single-crystal X-ray structures revealed that 5 and 6 are connected by two hexa …

This Review outlines the progress in the field of synthetic expanded carbaporphyrinoids.
The evolution of this topic is demonstrated with expanded porphyrin‐inspired systems with a …

The analogue of octaphyrin (1.1. 1.0. 1.1. 1.0) bearing two dimethoxyphenanthrene units
was synthesized and characterized in solution and solid state. The macrocycle was …

The unique environment within the core of carbaporphyrinoid systems provides a platform to
explore unusual organometallic chemistry. The ability of these structures to form stable …

Controlling the aromaticity in expanded porphyrins is a forefront research topic, and the
strategy of using protonation-triggered conformational changes to fine-tune electronic …

Replacement of the m-phenylene moiety of m-benziporphyrins with the 2, 7-naphthalenyl
subunit yielded 28-hetero-2, 7-naphthiporphyrins—macrocycles that can be considered as …

A series of complexes of metal halides with unreduced quinone-type ligands have been
synthesized and characterized in detail. The 3, 6-di-tert-butyl-o-benzoquinone (1) and 4, 6-di …

Abstract Di‐2, 7‐naphthihexaphyrin (1.1. 1.1. 1.1), a non‐aromatic carba‐analogue of the
hexaphyrin (1.1. 1.1. 1.1), incorporating two built‐in 2, 7‐naphthylene moieties was …