Parallel kinetic resolution of aziridines via chiral phosphoric acid-catalyzed apparent hydrolytic ring-opening

J Liu, YY Du, YS He, Y Liang, SZ Liu, YY Li… - Chemical Science, 2023 - pubs.rsc.org
We report a chiral phosphoric acid catalyzed apparent hydrolytic ring-opening reaction of
racemic aziridines in a regiodivergent parallel kinetic resolution manner. Harnessing the …

New Developments in Chiral Phosphoric Acid Catalysis for Amine Synthesis

BP Neupane, GK Friestad - Current Organic Chemistry, 2022 - benthamdirect.com
Asymmetric catalysis with chiral phosphoric acids (CPAs) has impacted a wide range of
organic reactions, including those that generate chiral amines of interest in medicinal and …

Parallel Kinetic Resolution through Palladium-Catalyzed Enantioselective Cycloimidoylation: En Route to Divergent N-Heterocycles Bearing a Quaternary …

X Wang, Y Luo, J Li, C Wang, Q Liu, Y He, S Luo… - ACS …, 2022 - ACS Publications
An example of a parallel kinetic resolution catalyzed by palladium to produce
enantioenriched five-and six-membered N-heterocycles in one pot was developed …

Intermolecular exo-selective Diels–Alder reaction catalysed by dual-functional Brønsted acid: conformational restriction of transition states by hydrogen bonds as the …

T Nakanishi, M Terada - RSC advances, 2023 - pubs.rsc.org
An exo-selective Diels–Alder (exo-DA) reaction in which the formed diastereomer is different
from that formed in the conventional endo-selective Diels–Alder (endo-DA) reaction was …

Development of chiral bisphosphoric acid/boronic acid co-catalyst system for enantioselective SN2'reaction

S Kayal, J Kikuchi, N Shinagawa, S Umemiya… - Tetrahedron, 2021 - Elsevier
An enantioselective intramolecular SN 2'reaction of geometrically defined allylic substrates
was developed by introducing a co-catalyst system composed of chiral bisphosphoric acid …

Catalyst‐Free Regioselective 1, 2‐Diheterofunctionalization of Vinylferrocene

P García‐Martínez, A Crespo… - European Journal of …, 2024 - Wiley Online Library
In this study, we report a catalyst‐free aminohalogenation process applied to vinylferrocene,
employing N‐halosuccinimides (NXS; X= Cl, Br, I) as dual nitrogen and halogen sources …

Chemodivergent Parallel Kinetic Resolution of Paracyclophanes: Enantiomer Fishing with Different Substrates

Q Liu, K Teng, Y Zhang, Y Lv, YR Chi, Z Jin - Angewandte Chemie - Wiley Online Library
An unprecedented chemodivergent strategy for parallel kinetic resolution (PKR) is disclosed
through which two planar chiral products bearing different structures were simultaneously …

Quinquevalent phosphorus acids

P Bałczewski, K Owsianik - 2024 - books.rsc.org
This chapter covers scientific contributions in quinquevalent organo-phosphorus chemistry
published in the literature in 2021. The review is not comprehensive but shows the most …