The role of oxygen vacancies in water oxidation for perovskite cobalt oxide electrocatalysts: are more better?

X Miao, L Wu, Y Lin, X Yuan, J Zhao, W Yan… - Chemical …, 2019 - pubs.rsc.org
We explore the role of oxygen vacancies in the oxygen evolution reaction (OER) for double
perovskite PrBaCo2O6− δ. Interestingly, we find that largely increasing oxygen vacancies …

Revealing the role of hydrogen in electron-doping mottronics for strongly correlated vanadium dioxide

X Zhou, H Li, F Meng, W Mao, J Wang… - The Journal of …, 2022 - ACS Publications
Hydrogen-associated electron-doping Mottronics for d-band correlated oxides (eg, VO2)
opens up a new paradigm to regulate the electronic functionality via directly manipulating …

A combined approach for comprehensive explanation of defects' thermodynamics in highly non-stoichiometric oxides: Case of RBaCo2O6-δ family (R= La, Nd, Pr, Sm …

IS Grobovoy, BV Politov, IR Shein… - Journal of Alloys and …, 2025 - Elsevier
The thermodynamics of defect formation in layered perovskite-like cobaltites RBaCo 2 O 6-δ
(R= La, Nd, Pr, Sm, Gd, Eu, Ho and Y) was investigated via two distinct methods–(I) …

Ionic order engineering in double-perovskite cobaltite

T Katayama, A Chikamatsu, Y Zhang, S Yasui… - Chemistry of …, 2021 - ACS Publications
Double-perovskite GdBaCo2O5. 5 (GBCO) exhibits various fascinating features, including
temperature-and magnetic-field-induced ferromagnetic to antiferromagnetic phase transition …

Photo-induced antiferromagnetic-ferromagnetic and spin-state transition in a double-perovskite cobalt oxide thin film

Y Zhang, T Katayama, A Chikamatsu… - Communications …, 2022 - nature.com
Investigation of ultrafast dynamic behaviors can provide novel insights about the coupling
mechanisms among multiple degrees of freedom in condensed matters, such as lattice …

Large magnetovolume effect induced by embedding ferromagnetic clusters into antiferromagnetic matrix of cobaltite perovskite

P Miao, X Lin, A Koda, S Lee, Y Ishikawa… - Advanced …, 2017 - Wiley Online Library
Materials that show negative thermal expansion (NTE) have significant industrial merit
because they can be used to fabricate composites whose dimensions remain invariant upon …

X-Ray Spectroscopy of Cobaltites

VR Galakhov - Physics of Metals and Metallography, 2021 - Springer
The ability of cobalt to take, depending on the temperature, pressure, and doping, various
charge and spin states in oxide compounds periodically becomes the topic of scientific …

Porous and highly conducting cathode material PrBaCo 2 O 6− δ: bulk and surface studies of synthesis anomalies

AS Bangwal, PK Jha, PK Dubey, MK Singh… - Physical Chemistry …, 2019 - pubs.rsc.org
The paradigm that chemical synthesis reduces the sintering temperature as compared to
solid state synthesis seems to be violated in the case of the PrBaCo2O6− δ double …

Influence of oxygen stoichiometry on Co3+ spin state transitions and magnetic properties in EuBaCo2O5+ δ cobaltites

A Kumari, C Dhanasekhar, V Adyam, AK Das - Journal of Magnetism and …, 2023 - Elsevier
The layered EuBaCo 2 O 5+ δ (δ= 0.47)(EBCO) cobaltite shows various magnetic phases at
high temperature and magnetic glassy state at low temperature. Further, the various …

X-Ray Absorption Co L Spectra for the Determination of the Charge and Spin States of Cobalt Ions in LnBaCo2O5 + δ Cobaltites (Ln = Eu, Gd, Tb)

VR Galakhov, MS Udintseva, SV Naumov, SN Shamin… - JETP Letters, 2022 - Springer
Co L X-ray absorption spectra were used to determine the charge and spin states of ions in
LnBaCo2O5+ δ cobaltites (Ln= Tb, Eu and Gd,). It is shown that with a decrease in the …