Degradation strategies for structural characterization of insoluble synthetic polymers by mass spectrometry
TNJ Fouquet, RB Cody… - Mass Spectrometry …, 2024 - Wiley Online Library
With the advent of soft ionization techniques such as electrospray (ESI) and matrix‐assisted
laser desorption/ionization (MALDI) to produce intact gas‐phase ions from nonvolatile …
laser desorption/ionization (MALDI) to produce intact gas‐phase ions from nonvolatile …
Deciphering Siloxane Bond Exchanges: From a Molecular Study to Vitrimerization and Recycling of Silicone Elastomers
DZ Khedaioui, C Tribout, J Bratasanu… - Angewandte Chemie …, 2023 - Wiley Online Library
The activity of various additives promoting siloxane equilibration reactions is examined and
quantified on model compounds. We found in particular that the “superbase” phosphazene …
quantified on model compounds. We found in particular that the “superbase” phosphazene …
Zinc‐catalyzed depolymerization of end‐of‐life polysiloxanes
S Enthaler - Angewandte Chemie, 2014 - Wiley Online Library
Polymers occupy an important role in our current society. Besides their great success, an
issue is the accumulation of huge amounts of end‐of‐life polymers. Currently, the waste …
issue is the accumulation of huge amounts of end‐of‐life polymers. Currently, the waste …
Solvothermal alcoholysis method for recycling high-consistency silicone rubber waste
R Petrus, J Utko, R Gniłka, MG Fleszar, T Lis… - …, 2021 - ACS Publications
In this work, we investigated the potential use of high-consistency silicone rubber (SR),
which is a synthetic solid material used in numerous industrial applications, to produce a …
which is a synthetic solid material used in numerous industrial applications, to produce a …
High-resolution Kendrick mass defect analysis of poly (ethylene oxide)-based non-ionic surfactants and their degradation products
T Fouquet, H Shimada, K Maeno, K Ito… - Journal of Oleo …, 2017 - jstage.jst.go.jp
Matrix assisted laser desorption ionization (MALDI) high-resolution mass spectrometry
(HRMS) and the recently introduced high-resolution Kendrick mass defect (HRKMD) …
(HRMS) and the recently introduced high-resolution Kendrick mass defect (HRKMD) …
Capabilities and limitations of direct analysis in real time orbitrap mass spectrometry and tandem mass spectrometry for the analysis of synthetic and natural polymers
MC Bridoux… - Rapid Communications in …, 2013 - Wiley Online Library
RATIONALE Despite the widespread use of direct analysis in real time mass spectrometry
(DART‐MS), its capabilities in terms of accessible mass range and the types of polymers that …
(DART‐MS), its capabilities in terms of accessible mass range and the types of polymers that …
Low‐temperature depolymerization of polysiloxanes with iron catalysis
S Enthaler, R Kretschmer - ChemSusChem, 2014 - Wiley Online Library
The easy accessibility and high adjustability of polymers mainly accounts for the great
impact of such materials on modern society. Besides this great success, an important matter …
impact of such materials on modern society. Besides this great success, an important matter …
Depolymerization by transition metal complexes: strategic approaches to convert polymeric waste to feedstocks
At present, plastic pollution is a global environmental catastrophe and a major threat to
mankind. Moreover, increased scale of manufacture of various plastic products is causing …
mankind. Moreover, increased scale of manufacture of various plastic products is causing …
Recycling concept for end-of-life silicones: Boron trifluoride diethyl etherate as depolymerization reagent to produce difluorodimethylsilane as useful commodity
P Döhlert, J Pfrommer, S Enthaler - ACS Sustainable Chemistry …, 2015 - ACS Publications
The current waste management system is based primarily on landfills, thermal recycling and
down-cycling. On the other hand, only a small portion of the end-of-life materials is recycled …
down-cycling. On the other hand, only a small portion of the end-of-life materials is recycled …
Iron‐catalyzed depolymerization of polysiloxanes to produce dichlorodimethylsilane, diacetoxydimethylsilane, or dimethoxydimethylsilane
S Enthaler - Journal of Applied Polymer Science, 2015 - Wiley Online Library
Polymers are one of the important pillars of our current society. Besides the great success a
matter is the accumulation of huge amounts of end‐of‐life polymers. Current waste …
matter is the accumulation of huge amounts of end‐of‐life polymers. Current waste …