New advances in nanographene chemistry

A Narita, XY Wang, X Feng, K Müllen - Chemical Society Reviews, 2015 - pubs.rsc.org
Nanographenes, or extended polycyclic aromatic hydrocarbons, have been attracting
renewed and more widespread attention since the first experimental demonstration of …

Corannulene: A curved polyarene building block for the construction of functional materials

MC Stuparu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus This Account describes a body of research in the design and synthesis of
molecular materials prepared from corannulene. Corannulene (C20H10) is a molecular …

Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications

E Nestoros, MC Stuparu - Chemical Communications, 2018 - pubs.rsc.org
Unlike typical polycyclic aromatic hydrocarbons, such as coronene, which are flat and
planar, corannulene is a molecular bowl of carbon. It can be imagined as the cap region of …

Benzene‐Fused Azacorannulene Bearing an Internal Nitrogen Atom

S Ito, Y Tokimaru, K Nozaki - Angewandte Chemie, 2015 - Wiley Online Library
A novel nitrogen‐doped corannulene derivative, 8‐tert‐butyl‐6b2‐azapentabenzo [bc, ef, hi,
kl, no] corannulene, was synthesized by 1, 3‐dipolar cycloaddition of a polycyclic aromatic …

Macromolecular architectures of corannulene: synthesis, properties, and applications of polymers containing a molecular bowl of carbon

MC Stuparu - Chemistry of Materials, 2023 - ACS Publications
Corannulene (C20H10) is a bowl-shaped polycyclic aromatic hydrocarbon. The molecular
curvature endows corannulene with a dipole moment, affinity for electrons, and the capacity …

Synthesis of corannulene-based nanographenes

EM Muzammil, D Halilovic, MC Stuparu - Communications Chemistry, 2019 - nature.com
Abstract Corannulene (C20H10) is a polycyclic hydrocarbon in which five six-membered
rings surround a central five-membered ring to construct a bowl-like aromatic structure. Here …

Buckybowls: Corannulene and its derivatives

X Li, F Kang, M Inagaki - Small, 2016 - Wiley Online Library
Corannulene, a kind of bowl like polycyclic aromatic hydrocarbon (PAH), whose molecule is
composed of a central pentagon and five closely adjacent hexagons on the pentagon's five …

Mechanochemical synthesis of corannulene: Scalable and efficient preparation of a curved polycyclic aromatic hydrocarbon under ball milling conditions

G Báti, S Laxmi, MC Stuparu - ChemSusChem, 2023 - Wiley Online Library
Corannulene, a curved polycyclic aromatic hydrocarbon, is prepared in a multigram scale
through mechanochemical synthesis. Initially, a mixer mill approach is examined and found …

Remarkable nonlinear optical response of pyrazine-fused trichalcogenasumanenes and their application for optical power limiting

J Sun, Y Sun, C Yan, D Lin, Z Xie, S Zhou… - Journal of Materials …, 2018 - pubs.rsc.org
The C3v-symmetric hetera buckybowl trichalcogenasumanenes have attracted recent
interest due to their unique features in chemical and optoelectronic aspects. To gain a …

Corannulene derivatives for organic electronics: From molecular engineering to applications

R Chen, RQ Lu, PC Shi, XY Cao - Chinese Chemical Letters, 2016 - Elsevier
This paper intends to provide an overview for using corannulene derivatives in organic
electronics such as organic field-effect transistors (OFETs), organic solar cells (OSCs), and …