Oxo-centered trinuclear ruthenium acetates: Structure and applications
S Nikolaou, LGA do Nascimento… - Coordination Chemistry …, 2023 - Elsevier
Polynuclear μ-oxo complexes are commonly observed for second and third row transition
metals. This review is particularly interested in the μ 3-oxo-bridged ruthenium trinuclear …
metals. This review is particularly interested in the μ 3-oxo-bridged ruthenium trinuclear …
A synthetic strategy for switching the single ion anisotropy in tetrahedral Co (II) complexes
Four novel mononuclear tetrahedral cobalt (II) complexes containing exocyclic mesoionic
ligands of molecular formulae [CoII (L1)(X) 2 (MeCN)] X= Cl (1) or Br (2) and [CoII (L2)(X) 2 …
ligands of molecular formulae [CoII (L1)(X) 2 (MeCN)] X= Cl (1) or Br (2) and [CoII (L2)(X) 2 …
Discrete, Cationic Palladium (II)‐Oxo Clusters via f‐Metal Ion Incorporation and their Macrocyclic Host‐Guest Interactions with Sulfonatocalixarenes
S Bhattacharya, A Barba‐Bon… - Angewandte Chemie …, 2022 - Wiley Online Library
We report on the discovery of the first two examples of cationic palladium (II)‐oxo clusters
(POCs) containing f‐metal ions,[PdII6O12M8 {(CH3) 2AsO2} 16 (H2O) 8] 4+(M= CeIV, ThIV) …
(POCs) containing f‐metal ions,[PdII6O12M8 {(CH3) 2AsO2} 16 (H2O) 8] 4+(M= CeIV, ThIV) …
Nickel(II)–Lanthanide(III) Magnetic Exchange Coupling Influencing Single‐Molecule Magnetic Features in {Ni2Ln2} Complexes
Abstract Four isostructural [Ni2Ln2 (CH3CO2) 3 (HL) 4 (H2O) 2] 3+(Ln3+= Dy (1), Tb (2), Ho
(3) or Lu (4)) complexes and a dinuclear [NiGd (HL) 2 (NO3) 3](5) complex are reported …
(3) or Lu (4)) complexes and a dinuclear [NiGd (HL) 2 (NO3) 3](5) complex are reported …
Discovery of a Neutral 40-PdII-Oxo Molecular Disk, [Pd40O24(OH)16{(CH3)2AsO2}16]: Synthesis, Structural Characterization, and Catalytic Studies
S Bhattacharya, X Ma, AS Mougharbel… - Inorganic …, 2021 - ACS Publications
We report on the synthesis and structural characterization of a giant, discrete, and neutral
molecular disk,[Pd40O24 (OH) 16 {(CH3) 2AsO2} 16](Pd 40), comprising a 40-palladium …
molecular disk,[Pd40O24 (OH) 16 {(CH3) 2AsO2} 16](Pd 40), comprising a 40-palladium …
Discovery and Supramolecular Interactions of Neutral Palladium‐Oxo Clusters Pd16 and Pd24
We report on the synthesis, structure, and physicochemical characterization of the first three
examples of neutral palladium‐oxo clusters (POCs). The 16‐palladium (II)‐oxo cluster …
examples of neutral palladium‐oxo clusters (POCs). The 16‐palladium (II)‐oxo cluster …
Influence of the ligand field on the slow relaxation of magnetization of unsymmetrical monomeric lanthanide complexes: synthesis and theoretical studies
A series of monomeric lanthanide Schiff base complexes with the molecular formulas [Ce
(HL) 3 (NO3) 3](1) and [Ln (HL) 2 (NO3) 3], where LnIII= Tb (2), Ho (3), Er (4), and Lu (5) …
(HL) 3 (NO3) 3](1) and [Ln (HL) 2 (NO3) 3], where LnIII= Tb (2), Ho (3), Er (4), and Lu (5) …
Probing the magnetic and magnetothermal properties of M (II)–Ln (III) complexes (where M (II)= Ni or Zn; Ln (III)= La or Pr or Gd)
We establish the coordination potential of the Schiff base ligand (2-methoxy-6-[(E)-2′-
hydroxymethyl-phenyliminomethyl]-phenolate (H2L)) via the isolation of various M (II)–Ln …
hydroxymethyl-phenyliminomethyl]-phenolate (H2L)) via the isolation of various M (II)–Ln …
The first 4d/4f single-molecule magnet containing a {Ru III 2 Dy III 2} core
SK Langley, DP Wielechowski, V Vieru… - Chemical …, 2015 - pubs.rsc.org
We report the synthesis, structure and magnetic properties of the first 4d–4f single-molecule
magnet. The complex [RuIII2DyIII2 (OMe) 2 (O2CPh) 4 (mdea) 2 (NO3) 2] displays a butterfly …
magnet. The complex [RuIII2DyIII2 (OMe) 2 (O2CPh) 4 (mdea) 2 (NO3) 2] displays a butterfly …
Three series of heterometallic Ni II–Ln III Schiff base complexes: synthesis, crystal structures and magnetic characterization
L Jiang, Y Liu, X Liu, J Tian, S Yan - Dalton Transactions, 2017 - pubs.rsc.org
Three series of NiII–LnIII complexes were synthesized with the general formulae [(μ3-CO3) 2
{Ni (HL)(CH3–CH2OH) Ln (CH3COO)} 2]· 2CH3CH2OH (1–6)(Ln= Tb (1), Dy (2), Ho (3), Er …
{Ni (HL)(CH3–CH2OH) Ln (CH3COO)} 2]· 2CH3CH2OH (1–6)(Ln= Tb (1), Dy (2), Ho (3), Er …