Oxo-centered trinuclear ruthenium acetates: Structure and applications

S Nikolaou, LGA do Nascimento… - Coordination Chemistry …, 2023 - Elsevier
Polynuclear μ-oxo complexes are commonly observed for second and third row transition
metals. This review is particularly interested in the μ 3-oxo-bridged ruthenium trinuclear …

A synthetic strategy for switching the single ion anisotropy in tetrahedral Co (II) complexes

S Vaidya, A Upadhyay, SK Singh, T Gupta… - Chemical …, 2015 - pubs.rsc.org
Four novel mononuclear tetrahedral cobalt (II) complexes containing exocyclic mesoionic
ligands of molecular formulae [CoII (L1)(X) 2 (MeCN)] X= Cl (1) or Br (2) and [CoII (L2)(X) 2 …

Discrete, Cationic Palladium (II)‐Oxo Clusters via f‐Metal Ion Incorporation and their Macrocyclic Host‐Guest Interactions with Sulfonatocalixarenes

S Bhattacharya, A Barba‐Bon… - Angewandte Chemie …, 2022 - Wiley Online Library
We report on the discovery of the first two examples of cationic palladium (II)‐oxo clusters
(POCs) containing f‐metal ions,[PdII6O12M8 {(CH3) 2AsO2} 16 (H2O) 8] 4+(M= CeIV, ThIV) …

Nickel(II)–Lanthanide(III) Magnetic Exchange Coupling Influencing Single‐Molecule Magnetic Features in {Ni2Ln2} Complexes

N Ahmed, C Das, S Vaidya, SK Langley… - … A European Journal, 2014 - Wiley Online Library
Abstract Four isostructural [Ni2Ln2 (CH3CO2) 3 (HL) 4 (H2O) 2] 3+(Ln3+= Dy (1), Tb (2), Ho
(3) or Lu (4)) complexes and a dinuclear [NiGd (HL) 2 (NO3) 3](5) complex are reported …

Discovery of a Neutral 40-PdII-Oxo Molecular Disk, [Pd40O24(OH)16{(CH3)2AsO2}16]: Synthesis, Structural Characterization, and Catalytic Studies

S Bhattacharya, X Ma, AS Mougharbel… - Inorganic …, 2021 - ACS Publications
We report on the synthesis and structural characterization of a giant, discrete, and neutral
molecular disk,[Pd40O24 (OH) 16 {(CH3) 2AsO2} 16](Pd 40), comprising a 40-palladium …

Discovery and Supramolecular Interactions of Neutral Palladium‐Oxo Clusters Pd16 and Pd24

S Bhattacharya, U Basu, M Haouas, P Su… - Angewandte …, 2021 - Wiley Online Library
We report on the synthesis, structure, and physicochemical characterization of the first three
examples of neutral palladium‐oxo clusters (POCs). The 16‐palladium (II)‐oxo cluster …

Influence of the ligand field on the slow relaxation of magnetization of unsymmetrical monomeric lanthanide complexes: synthesis and theoretical studies

A Upadhyay, KR Vignesh, C Das, SK Singh… - Inorganic …, 2017 - ACS Publications
A series of monomeric lanthanide Schiff base complexes with the molecular formulas [Ce
(HL) 3 (NO3) 3](1) and [Ln (HL) 2 (NO3) 3], where LnIII= Tb (2), Ho (3), Er (4), and Lu (5) …

Probing the magnetic and magnetothermal properties of M (II)–Ln (III) complexes (where M (II)= Ni or Zn; Ln (III)= La or Pr or Gd)

N Ahmed, C Das, S Vaidya, AK Srivastava… - Dalton …, 2014 - pubs.rsc.org
We establish the coordination potential of the Schiff base ligand (2-methoxy-6-[(E)-2′-
hydroxymethyl-phenyliminomethyl]-phenolate (H2L)) via the isolation of various M (II)–Ln …

The first 4d/4f single-molecule magnet containing a {Ru III 2 Dy III 2} core

SK Langley, DP Wielechowski, V Vieru… - Chemical …, 2015 - pubs.rsc.org
We report the synthesis, structure and magnetic properties of the first 4d–4f single-molecule
magnet. The complex [RuIII2DyIII2 (OMe) 2 (O2CPh) 4 (mdea) 2 (NO3) 2] displays a butterfly …

Three series of heterometallic Ni II–Ln III Schiff base complexes: synthesis, crystal structures and magnetic characterization

L Jiang, Y Liu, X Liu, J Tian, S Yan - Dalton Transactions, 2017 - pubs.rsc.org
Three series of NiII–LnIII complexes were synthesized with the general formulae [(μ3-CO3) 2
{Ni (HL)(CH3–CH2OH) Ln (CH3COO)} 2]· 2CH3CH2OH (1–6)(Ln= Tb (1), Dy (2), Ho (3), Er …