Sulfonyl hydrazides are widely used as organic reagents. Advances in the past decade are
summarized in the following categories by key intermediates:(1)[RO2S.];(2) …

This review mainly focuses on recent developments in the preparation of β-keto sulfones
and their extensive synthetic applications. New prospects for the synthesis of β-keto …

Recent advances in the sulfonylation reactions by using inorganic sulfites as the source of
sulfonyl group are reported. The approaches employing inorganic sulfites as sulfur dioxide …

The reactivity of diazoalkanes most commonly proceeds through the formation of carbene
intermediates or dipolar cycloaddition reactions. The reaction of diazoalkanes with …

This work demonstrates the synthesis of a variety of perfluoroalkyl heterocycles via a visible-
light-driven radical-polar crossover cyclization strategy. In this process, single-electron …

Sulfonylated N-unsubstituted enamines were synthesized through a chain of chemical and
electrochemical transformations via sulfonylation of vinyl azides. The disclosing of the N …

The ring-opening of small-ring compounds is an important topic in organic synthesis due to
its ability to enable the reconstruction and reorganization of existing structures to form new …

Oxosulfonylation is a difunctionalization protocol where oxo and sulfonyl groups are
introduced in one step to construct ketosulfones and N‐acylsulfonamides from simple and …

Sulfonylation of the benzylic C–H bond is developed through a three-component reaction of
aryldiazonium tetrafluoroborates, 4-methylphenols and sodium metabisulfite (Na2S2O5) …

A copper/cobalt-catalyzed difunctionalization of alkenes with sulfonylazides and tert-butyl
hydroperoxide has been achieved. This protocol provides an efficient and direct …