Si–B reagents, namely silylboronic esters and silylboranes, have become increasingly
attractive as versatile reagents to introduce silicon and boron atoms into organic …

In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …

Organosilicon compounds act as a nucleophile upon activation by an appropriate base and
behave in a manner similar to main-group organometallic reagents. In the last decades …

The metal-catalysed successive activation and functionalisation of sp2 C–H bonds is the at
heart of synthetic innovations for the development of C–C bond cross-coupling processes …

A study on the iridium-catalyzed C–H borylation of heteroarenes is reported. Several
heteroarenes containing multiple heteroatoms were found to be amenable to C–H borylation …

Organoboronic acids and their derivatives are useful reagents in carbon–carbon and carbon–
heteroatom bond formations. 1 In addition to having reasonable reactivities, organoboronic …

The selective functionalization of strong, typically inert carbon-hydrogen (C–H) bonds in
organic molecules is changing synthetic chemistry. However, the undirected …

Cobalt dialkyl and bis (carboxylate) complexes bearing α-diimine ligands have been
synthesized and demonstrated as active for the C (sp3)-H borylation of a range of …

With the aid of high-throughput screening, the efficiency of Ir-catalyzed C–H borylations has
been assessed as functions of precatalyst, boron reagent, ligand, order of addition …

We report herein an efficient and general method for the deboronofluorination of
alkylboronates. Thus, with the catalysis of AgNO3, the reactions of various alkylboronic acids …