The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present
review, reactions catalyzed by homogeneous and supported vanadium complexes from …

Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic
Applications | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In …

Proximity-driven metalation has been extensively exploited to achieve reactivity and
selectivity in carbon–hydrogen (C–H) bond activation. Despite the substantial improvement …

Achieving site selectivity in C–H functionalization reactions is a significant challenge,
especially when the target C–H bond is distant from existing functional groups …

Catalytic asymmetric dearomatization (CADA) reactions refer to those reactions converting
aromatic compounds into enantio-enriched three-dimensional cyclic molecules in a catalytic …

Herein, we report visible light and N-heterocyclic carbene (NHC) jointly promoted
multicomponent carbene transfer reactions. Under the optimized reaction conditions, two …

Historically, reagent controlled reactions (mechanism controlled reactions) have played a
significant role in the asymmetric synthesis of complex structures. In contrast, today's …

A simple, efficient, and environmentally friendly asymmetric epoxidation of primary,
secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process …

The chiral sulfide, isothiocineole, has been synthesized in one step from elemental sulfur, γ-
terpinene, and limonene in 61% yield. A mechanism involving radical intermediates for this …

A Pd-catalyzed C–O cross-coupling of O-acyl hydroxylamines and tertiary or secondary alkyl
electrophiles was reported without the cleavage of the rather fragile N–O bond. The …