Mechanistic studies of relevance to the biological activities of chromium

A Levina, PA Lay - Coordination Chemistry Reviews, 2005 - Elsevier
Cellular uptake of Cr (VI), followed by its reduction to Cr (III) with the formation of reactive Cr
(V/IV) intermediates, is a generally accepted cause of Cr (VI)-induced genotoxicity and …

The Kinetics and Mechanism of Oxidation of Triethylenetetraaminehexaacetatocobaltate (II) Complex by Periodate Ion in AqueousMedium

RM Naik, A Srivastava, AK Verma… - BioInorganic Reaction …, 2007 - degruyter.com
The Kinetics and Mechanism of Oxidation of Triethylenetetraaminehexaacetatocobaltate(II)
Complex by Periodate Ion in Aqueous Med Page 1 Inorganic Reaction Mechanisims, Vol. 6 …

Kinetics and Mechanism of Oxidation of Chromium (III)‐guanosine 5‐Monophosphate Complex by Periodate

HA Ewais, SA Ahmed… - Journal of the Chinese …, 2004 - Wiley Online Library
The kinetics of oxidation of the chromium (III)‐guanosine 5‐monophosphate complex,[CrIII
(L)(H2O) 4] 3+(L= guanosine 5‐monophosphate) by periodate in aqueous solution to CrVI …

Kinetics and mechanism of oxidation of iminodiacetatochromium (III) by periodate

HA Ewais, FD Al-Otaibi… - BioInorganic Reaction …, 2006 - degruyter.com
The kinetics of oxidation of the chromium (III)-iminodiacetic acid complex,[CrIII
(HIDA)(IDA)(H2O)] by periodate in aqueous solution to CrVI have been studied …

Kinetics and mechanism of oxidation of cis-diaquabis(glycinato)chromium(III) by periodate ion in aqueous solutions

IH Ali, Y Sulfab - Transition Metal Chemistry, 2013 - Springer
The kinetics of oxidation of cis-Cr III (gly) 2 (H 2 O) 2+(gly= glycinate) by IO _ 4^-has been
studied in aqueous solutions. The reaction is first order in the chromium (III) complex …

Concurrent two one‐electron transfer in the oxidation of chromium(III) complexes with trans‐1,2‐diaminocyclohexane‐N,N,N′,N′‐tetraacetate and …

IH Ali, Y Sulfab - International Journal of Chemical Kinetics, 2012 - Wiley Online Library
The kinetics of oxidation of [CrIIIcdta (H2O)]− and [CrIIIdtpa (H2O)] 2−(where cdta= trans‐1, 2‐
diaminocyclohexane‐N, N, N′, N′‐tetraacetate and dtpa= diethylenetriaminepentaacetate …

Kinetics and mechanism of oxidation of chromium (III)-guanosine complex by periodate

HA EWAIS, SA AHMED… - BioInorganic Reaction …, 2004 - degruyter.com
The oxidation kinetics of the chromium (III)-guanosine complex,[CrIII (G)(H2O) 4] 3+(G=
guanosine) with periodate in aqueous solution were studied and found to obey the rate law …

Kinetics and mechanism of the one‐step, two‐electron oxidation of diaquadichloro (1, 10‐phenanthroline) chromium (III) chloride dihydrate by periodate to chromium …

SB Eltahir, IH Ali, Y Sulfab - International Journal of Chemical …, 2021 - Wiley Online Library
The kinetics of oxidation of [CrIIICl2 (phen)(H2O) 2] Cl⋅ 2H2O (phen= 1, 10‐phenanthroline)
by periodate {I (VII)} have been studied in aqueous acidic solutions. The oxidation product …

Mechanism of electron transfer reaction of ternary nitrilotriacetatocobalt (II) complexes involving succinate and malonate as secondary ligands

HA Ewais - International Journal of Chemical Kinetics, 2008 - Wiley Online Library
The mechanism of oxidation of ternary complexes,[CoII (nta)(S)(H2O) 2] 3− and [CoII
(nta)(M)(H2O)] 3−(nta= nitrilotriacetate acid, S= succinate dianion, and M= malonate …

Opportunity to recycle chromium(VI) by in situ electro‐oxidation

H Lateef, SM Grimes, AJ Chaudhary… - Journal of Chemical …, 2009 - Wiley Online Library
BACKGROUND: Chemical oxidation is generally used to oxidise Cr (III) to Cr (VI) in aqueous
effluents, but this leads to Cr (VI) solutions that are contaminated with oxidising agents …