Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Light-controlled radical polymerization: mechanisms, methods, and applications

M Chen, M Zhong, JA Johnson - Chemical reviews, 2016 - ACS Publications
The use of light to mediate controlled radical polymerization has emerged as a powerful
strategy for rational polymer synthesis and advanced materials fabrication. This review …

Redox-active polymers for energy storage nanoarchitectonics

J Kim, JH Kim, K Ariga - Joule, 2017 - cell.com
Recently, one of the most important scientific issues for a better future life for humanity is
achieving the ability to intelligently harvest, store, and utilize energy with good efficiency …

Photoinduced electron transfer reactions for macromolecular syntheses

S Dadashi-Silab, S Doran, Y Yagci - Chemical reviews, 2016 - ACS Publications
Photochemical reactions, particularly those involving photoinduced electron transfer
processes, establish a substantial contribution to the modern synthetic chemistry, and the …

Externally controlled atom transfer radical polymerization

X Pan, M Fantin, F Yuan, K Matyjaszewski - Chemical Society Reviews, 2018 - pubs.rsc.org
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …

Synthesizing biomaterials in living organisms

X Zhang, J Wang, Y Zhang, Z Yang, J Gao… - Chemical Society …, 2023 - pubs.rsc.org
Living organisms fabricate biomacromolecules such as DNA, RNA, and proteins by the self-
assembly process. The research on the mechanism of biomacromolecule formation also …