Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …

Here we describe the discovery of a new class of C–H borylation catalysts and their use for
regioselective C–H borylation of aromatic, heteroaromatic, and aliphatic systems. The new …

Abstract The Suzuki–Miyaura cross-coupling of organoboron nucleophiles with aryl halide
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …

pH–rate profiles for aqueous–organic protodeboronation of 18 boronic acids, many widely
viewed as unstable, have been studied by NMR and DFT. Rates were pH-dependent, and …

A study on the iridium-catalyzed C–H borylation of heteroarenes is reported. Several
heteroarenes containing multiple heteroatoms were found to be amenable to C–H borylation …

An efficient strategy for the para-selective borylation of aromatic esters is described. For
achieving high para-selectivity, a new catalytic system has been developed modifying the …

Palladium-catalysed cross-coupling reactions constitute a powerful class of chemical
methods for the creation of carbon-carbon and carbon-heteroatom bonds used in organic …

The iridium‐catalysed borylation of aromatic C− H bonds has become the preferred method
for the synthesis of aromatic organoboron compounds. The reaction is highly efficient …

Major new advances in synthetic chemistry methods are typically reported using simple, non-
standardized reaction substrates, and reaction failures are rarely documented. This makes …