Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Understanding ligand-protected noble metal nanoclusters at work

MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …

Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Chiral inorganic nanostructures

W Ma, L Xu, AF de Moura, X Wu, H Kuang, C Xu… - Chemical …, 2017 - ACS Publications
The field of chiral inorganic nanostructures is rapidly expanding. It started from the
observation of strong circular dichroism during the synthesis of individual nanoparticles …

Toward total synthesis of thiolate-protected metal nanoclusters

Q Yao, T Chen, X Yuan, J Xie - Accounts of chemical research, 2018 - ACS Publications
Conspectus Total synthesis, where desired organic-and/or biomolecules could be produced
from simple precursors at atomic precision and with known step-by-step reactions, has …

Dicarboxylic acids induced tandem transformation of silver nanocluster

Z Wang, RK Gupta, F Alkan, BL Han… - Journal of the …, 2023 - ACS Publications
Structural transformation of metal nanoclusters (NCs) is of great ongoing interest regarding
their synthesis, stability, and reactivity. Although sporadic examples of cluster …

Luminescent metal nanoclusters with aggregation-induced emission

N Goswami, Q Yao, Z Luo, J Li, T Chen… - The journal of physical …, 2016 - ACS Publications
Thiolate-protected metal nanoclusters (or thiolated metal NCs) have recently emerged as a
promising class of functional materials because of their well-defined molecular structures …

[HTML][HTML] Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

[HTML][HTML] Dynamic and transformable Cu12 cluster-based CH···π-stacked porous supramolecular frameworks

C Zhang, Z Wang, WD Si, H Chu, L Zhou, T Li… - Nature …, 2023 - nature.com
The assembly of cluster-based π-stacked porous supramolecular frameworks presents
daunting challenges, including the design of suitable cluster building units, control of the …