Boron: its role in energy‐related processes and applications
Z Huang, S Wang, RD Dewhurst… - Angewandte Chemie …, 2020 - Wiley Online Library
Boron's unique position in the Periodic Table, that is, at the apex of the line separating
metals and nonmetals, makes it highly versatile in chemical reactions and applications …
metals and nonmetals, makes it highly versatile in chemical reactions and applications …
Single─Not Double─3D-Aromaticity in an Oxidized Closo Icosahedral Dodecaiodo-Dodecaborate Cluster
3D-aromatic molecules with (distorted) tetrahedral, octahedral, or spherical structures are
much less common than typical 2D-aromatic species or even 2D-aromatic-in-3D systems …
much less common than typical 2D-aromatic species or even 2D-aromatic-in-3D systems …
Controlled Formation of Fused Metal Chalcogenide Nanoclusters Using Soft Landing of Gaseous Fragment Ions
The complete ligation of nanoclusters significantly reduces their chemical reactivity, catalytic
activity, and charge transfer properties. Therefore, in applications, nanoclusters are activated …
activity, and charge transfer properties. Therefore, in applications, nanoclusters are activated …
Gas-phase ion chemistry of [B12X12] 2−(X= F, Cl, Br, I, CN) A brief review of twelve years of researching twelve− vertexed dianions and their fragments
J Warneke - International Journal of Mass Spectrometry, 2023 - Elsevier
The closo-dodecaborate dianions [B 12 X 12] 2−(X= halogen, CN) have been recognized in
recent years for their outstanding physical and chemical properties. Gas-phase ion …
recent years for their outstanding physical and chemical properties. Gas-phase ion …
Rational design of an argon-binding superelectrophilic anion
M Mayer, V Van Lessen… - Proceedings of the …, 2019 - National Acad Sciences
Chemically binding to argon (Ar) at room temperature has remained the privilege of the most
reactive electrophiles, all of which are cationic (or even dicationic) in nature. Herein, we …
reactive electrophiles, all of which are cationic (or even dicationic) in nature. Herein, we …
Influence of surface and intermolecular interactions on the properties of supported polyoxometalates
Polyoxometalates (POMs) with localized radical or open-shell metal sites have the potential
to be used as transformative electronic spin based molecular qubits (MQs) for quantum …
to be used as transformative electronic spin based molecular qubits (MQs) for quantum …
Self-organizing layers from complex molecular anions
The formation of traditional ionic materials occurs principally via joint accumulation of both
anions and cations. Herein, we describe a previously unreported phenomenon by which …
anions and cations. Herein, we describe a previously unreported phenomenon by which …
Binding Properties of Small Electrophilic Anions [B6X5]− and [B10X9]− (X=Cl, Br, I): Activation of Small Molecules Based on π‐Backbonding
Superelectrophilic anions constitute a special class of molecular anions that show strong
binding of weak nucleophiles despite their negative charge. In this study, the binding …
binding of weak nucleophiles despite their negative charge. In this study, the binding …
Beyond Duality: Rationalizing Repulsive Coulomb Barriers in Host–Guest Cyclodextrin–Dodecaborate Complexes
Y Jiang, Z Hu, Y Yang, P Peng, C Zhong… - The Journal of …, 2023 - ACS Publications
The repulsive Coulomb barrier (RCB), an intrinsic potential energy barrier along electron
detachment or charge-separation coordinates in multiply charged anions (MCAs), provides …
detachment or charge-separation coordinates in multiply charged anions (MCAs), provides …
A benchmark photoelectron spectroscopic and theoretical study of the electronic stability of [B12H12] 2−
We report a joint benchmark study on the electronic stability of closo-dodecaborate [B 12 H
12] 2− employing negative ion photoelectron spectroscopy and high level electronic …
12] 2− employing negative ion photoelectron spectroscopy and high level electronic …